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Cited by 326

The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.

Relativistic energies of the ground state of the hydrogen molecule

Wolniewicz, L.·1993·The Journal of Chemical Physics
DOI 10.1063/1.465303
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Abstract

Relativistic corrections, Born–Oppenheimer energies and adiabatic corrections are computed for R ≤ 12.0 bohr for the electronic ground state of the hydrogen molecule. The Born–Oppenheimer potential is slightly lower than ever reported. The problem of linear dependencies in the basis set is removed and the same set is used for all internuclear distances which assures continuity of the results. The radiative corrections are evaluated approximately and—for that purpose—the polarizability of the molecule is also computed. Vibrational energies are computed and— corrected for nonadiabatic effects—compared with experiment for several isotopes. It is argued on the basis of the remaining discrepancies that an improvement in the ab initio nonadiabatic corrections is necessary.

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Metadata

Authors
Wolniewicz, L.
Venue
The Journal of Chemical Physics
Publisher
AIP Publishing
Published
1993-08-01
Volume
99
Issue
3
Pages
1851-1868
ISSN
  • 0021-9606 (ISSN-L)
  • 1089-7690
DOI
10.1063/1.465303
OpenAlex
W2054092108
Cited by
326
References
11
FWCI
6.87
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Relativistic energies of the ground state of the hydrogen molecule. https://app.cochat.ai/papers/10.1063/1.465303
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Wolniewicz, L. (1993). Relativistic energies of the ground state of the hydrogen molecule. The Journal of Chemical Physics. https://doi.org/10.1063/1.465303

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.