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Cited by 377

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Revised structural phase diagram of (Ba0.7Ca0.3TiO3)-(BaZr0.2Ti0.8O3)

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Keeble, Dean S., Benabdallah, Feres, Thomas, Pam A., Maglione, Mario, Kreisel, Jens·2013·Applied Physics Letters

Abstract

The temperature-composition phase diagram of barium calcium titanate zirconate (x(Ba0.7Ca0.3TiO3)-(1 − x)(BaZr0.2Ti0.8O3); BCTZ) has been reinvestigated using high-resolution synchrotron x-ray powder diffraction. Contrary to previous reports of an unusual rhombohedral-tetragonal phase transition in this system, we have observed an intermediate orthorhombic phase, isostructural to that present in the parent phase, BaTiO3, and we identify the previously assigned T-R transition as a T-O transition. We also observe the O-R transition coalescing with the previously observed triple point, forming a phase convergence region. The implication of the orthorhombic phase in reconciling the exceptional piezoelectric properties with the surrounding phase diagram is discussed.

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Metadata

Authors
Keeble, D. S., Benabdallah, F., Thomas, P. A., Maglione, M., & Kreisel, J.
Venue
Applied Physics Letters
Published
2013-03-04
Volume
102
Issue
9
ISSN
  • 0003-6951 (ISSN-L)
  • 1077-3118
OpenAlex
W2018592047
Cited by
377
References
19
FWCI
13.91
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Revised structural phase diagram of (Ba0.7Ca0.3TiO3)-(BaZr0.2Ti0.8O3). https://app.cochat.ai/papers/10.1063/1.4793400
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Keeble, D. S., Benabdallah, F., Thomas, P. A., Maglione, M., & Kreisel, J. (2013). Revised structural phase diagram of (Ba0.7Ca0.3TiO3)-(BaZr0.2Ti0.8O3). Applied Physics Letters. https://doi.org/10.1063/1.4793400

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