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Homogeneous nucleation rates of supercooled water measured in single levitated microdroplets
Abstract
Homogeneous nucleation rates are determined for micrometer sized water droplets levitated inside an electrodynamic Paul-trap. The size of a single droplet is continuously measured by analyzing the angle-resolved light scattering pattern of the droplets with classical Mie theory. The freezing process is detected by a pronounced increase in the depolarization of the scattered light. By statistical analysis of the freezing process of some thousand individual droplets, we obtained the homogeneous nucleation rate of water between 236 and 237 K. The values are in agreement with former expansion cloud chamber measurements but could be determined with considerably higher precision. The measurements are discussed in the light of classical nucleation theory in order to obtain the size and the formation energy of the critical nucleus.
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Citations
Cites
Kinetische Behandlung der Keimbildung in übersättigten Dämpfen
Becker, R., & Döring, W. (1935) · Annalen der Physik · doi:10.1002/andp.19354160806 · Cited by 3,155
Cited by
Molecular dynamics simulation of the ice nucleation and growth process leading to water freezing
Matsumoto, M., Saito, S., & Ohmine, I. (2002) · Nature · doi:10.1038/416409a · Cited by 965
Homogeneous Ice Nucleation at Moderate Supercooling from Molecular Simulation
Sanz, E., Vega, C., Espinosa, J. R., Caballero-Bernal, R., Abascal, J. L. F., & Valeriani, C. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4028814 · Cited by 334
Metadata
- Authors
- Krämer, B., Hübner, O., Vortisch, H., Wöste, L., Leisner, T., Schwell, M., Rühl, E., & Baumgärtel, H.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1999-10-08
- Volume
- 111
- Issue
- 14
- Pages
- 6521-6527
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2054600704
- Cited by
- 176
- References
- 1
- FWCI
- 2.25
- Type
- journal article
- Language
- en
- Open access
- closed
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- Krämer, B., Hübner, O., Vortisch, H., Wöste, L., Leisner, T., Schwell, M., Rühl, E., & Baumgärtel, H. (1999). Homogeneous nucleation rates of supercooled water measured in single levitated microdroplets. The Journal of Chemical Physics. https://doi.org/10.1063/1.479946
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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