Preface: Special Topic on Multidimensional Spectroscopy
Abstract
Multidimensional signals are generated by subjecting molecules to sequences of short optical pulses and recording correlation plots related to the various controlled delay periods. These techniques which span all the way from the THz to the x-ray regimes provide qualitatively new structural and dynamical molecular information not available from conventional one-dimensional techniques. This issue surveys the recent experimental and theoretical progresses in this rapidly developing 20 year old field which illustrates the novel insights provided by multidimensional techniques into electronic and nuclear motions. It should serve as a valuable source for experts in the field and help introduce newcomers to this exciting and challenging branch of nonlinear spectroscopy.
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Multidimensional spectroscopic techniques probe the electronic structure and nuclear dynamics of molecules through their response to sequences of short pulses with variable, carefully timed delays.
“Multidimensional spectroscopic techniques, first developed in nuclear magnetic resonance [36], and gradually extended to higher frequency (infrared, and optical) regimes [37,38], probe the electronic structure and nuclear dynamics of molecules through their response to sequences of short pulses with variable, carefully timed delays.”
From Roadmap of ultrafast x-ray atomic and molecular physics (2018) · cites this paper as [38]
Cites
Elsaesser, T., Reimann, K., & Woerner, M. (2015) · The Journal of Chemical Physics · doi:10.1063/1.4916522 · Cited by 23 · see citing works
Franck, J. M., Chandrasekaran, S., Dzikovski, B. G., et al. (2015) · The Journal of Chemical Physics · doi:10.1063/1.4917322 · Cited by 20 · see citing works
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Roadmap of ultrafast x-ray atomic and molecular physics
Young, L., Ueda, K., Gühr, M., Bucksbaum, P. H., Simon, M., Mukamel, S., Rohringer, N., Prince, K. C., Masciovecchio, C., Meyer, M., et al. (2018) · Journal of Physics B: Atomic, Molecular and Optical Physics · doi:10.1088/1361-6455/aa9735 · Cited by 337 · see citing works
Self-citation
- Authors
- Mukamel, S., & Bakker, H. J.
- Affiliations
- University of California, Irvine (US)
- Institute for Atomic and Molecular Physics (NL)
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 2015-05-28
- Volume
- 142
- Issue
- 21
- Pages
- 212101-212101
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W1548018766
- Cited by
- 17
- References
- 2
- Citations by year
- 2026: 1 · 2025: 1 · 2022: 1 · 2020: 2 · 2019: 2 · 2018: 2 · 2017: 1 · 2016: 4 · 2015: 3
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- The Journal of Chemical Physics (publishedVersion)
- PubMed (publishedVersion)
- eScholarship (California Digital Library) (submittedVersion)
- Topics
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Spectroscopy and Quantum Chemical Studies
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Laser-Matter Interactions and Applications
- Physical Sciences › Chemistry › Spectroscopy › Molecular Spectroscopy and Structure
- Keywords
- multidimensional spectroscopy, nonlinear spectroscopy, correlation spectroscopy, ultrashort optical pulses, molecular dynamics, electronic dynamics, nuclear dynamics, time-resolved spectroscopy, terahertz spectroscopy, X-ray spectroscopy
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