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The Solubility of Carbon Dioxide in Water at Low Pressure

Carroll, John J., Slupsky, John D., Mather, Alan E.·1991·Journal of Physical and Chemical Reference Data

Abstract

The system carbon dioxide-water is of great scientific and technological importance. Thus, it has been studied often. The literature for the solubility of carbon dioxide in water is vast and interdisciplinary. An exhaustive survey was conducted and approximately 100 experimental investigations were found that reported equilibrium data at pressures below 1 MPa. A model based on Henry’s law was used to correlate the low pressure data (those up to 1 MPa). The following correlation of the Henry’s constants (expressed on a mole fraction basis) was developed ln(H21/MPa)=−6.8346+1.2817×104/T−3.7668×106/T2 +2.997×108/T3 The correlation is valid for 273<T<433 K(0<t<160 °C) where T is in K. Any experimental data that deviated significantly from this model were duly noted.

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Metadata

Authors
Carroll, J. J., Slupsky, J. D., & Mather, A. E.
Venue
Journal of Physical and Chemical Reference Data
Published
1991-11-01
Volume
20
Issue
6
Pages
1201-1209
ISSN
  • 0047-2689 (ISSN-L)
  • 1529-7845
OpenAlex
W1999524807
Cited by
708
References
0
FWCI
1.27
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: The Solubility of Carbon Dioxide in Water at Low Pressure. https://app.cochat.ai/papers/10.1063/1.555900
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Carroll, J. J., Slupsky, J. D., & Mather, A. E. (1991). The Solubility of Carbon Dioxide in Water at Low Pressure. Journal of Physical and Chemical Reference Data. https://doi.org/10.1063/1.555900

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.