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Bulk formation of a metallic glass: Pd40Ni40P20
Abstract
Molten spheroids of Pd40 Ni40 P20, of up to 0.53-cm minor diameter, were slowly cooled (1.4 K/s) on a fused silica surface under 10−6 Torr vacuum to a form which was entirely glassy except for some superficial crystallinity comprising less than 0.5% of the volume. The occurrence of crystallization was eliminated by subjecting the specimens to surface etching followed by a succession of heating and cooling cycles. The absence of crystallization in the bulk was confirmed by x-ray diffraction, transmission electron microscopy, and calorimetry. Using the last technique, the heat of crystallization of the glass was measured to be 5.3±0.3 kJ/g atom.
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Cited by
Bulk metallic glass formation in the binary Cu–Zr system
Wang, D., Li, Y., Sun, B. B., Sui, M. L., Lu, K., & Ma, E. (2004) · Applied Physics Letters · doi:10.1063/1.1751219 · Cited by 502
Containerless processing in the study of metallic melts and their solidification
Herlach, D. M., Cochrane, R. F., Egry, I., Fecht, H. J., & Greer, A. L. (1993) · International Materials Reviews · doi:10.1179/095066093790326267 · Cited by 340
Self-citationWang, Z., Li, M., Yu, J., Ge, X., Liu, Y., & Wang, W. (2020) · Advanced Materials · doi:10.1002/adma.201906384 · Cited by 138
Metadata
- Authors
- Drehman, A. J., Greer, A. L., & Turnbull, D.
- Venue
- Applied Physics Letters
- Publisher
- AIP Publishing
- Published
- 1982-10-15
- Volume
- 41
- Issue
- 8
- Pages
- 716-717
- ISSN
- 0003-6951 (ISSN-L)
- 1077-3118
- OpenAlex
- W2008438751
- Cited by
- 337
- References
- 0
- FWCI
- 8.31
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Bulk formation of a metallic glass: Pd40Ni40P20. https://app.cochat.ai/papers/10.1063/1.93645
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- Drehman, A. J., Greer, A. L., & Turnbull, D. (1982). Bulk formation of a metallic glass: Pd40Ni40P20. Applied Physics Letters. https://doi.org/10.1063/1.93645
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