Low‐Iridium‐Content IrNiTa Metallic Glass Films as Intrinsically Active Catalysts for Hydrogen Evolution Reaction
Abstract
Although various catalytic materials have emerged for hydrogen evolution reaction (HER), it remains crucial to develop intrinsically effective catalysts with minimum uses of expensive and scarce precious metals. Metallic glasses (MGs) or amorphous alloys show up as attractive HER catalysts, but have so far limited to material forms and compositions that result in high precious-metal loadings. Here, an Ir 25 Ni 33 Ta 42 MG nanofilm exhibiting high intrinsic activity and superior stability at an ultralow Ir loading of 8.14 µg cm -2 for HER in 0.5 m H 2 SO 4 is reported. With an overpotential of 99 mV for a current density of 10 mA cm -2 , a small Tafel slope of 35 mV dec -1 , and high turnover frequencies of 1.76 and 19.3 H 2 s -1 at 50 and 100 mV overpotentials, the glassy film is among the most intrinsically active HER catalysts, outcompetes any reported MG, representative sulfides, and phosphides, and compares favorably with other precious-metal-containing catalysts. The outstanding HER performance of the Ir 25 Ni 33 Ta 42 MG film is attributed to the synergistic effect of the novel alloy system and amorphous structure, which may inspire the development of multicomponent alloys for heterogeneous catalysis.
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F-SnO2@Pt also beat non-noble-metal-based catalysts such as the phosphide and MoS2 family by a fair margin.
“it also beat non-noble-metal-based catalysts such as the phosphide and MoS2 family by a fair margin”
From Highly Dispersed Pt Clusters on F-Doped Tin(IV) Oxide Aerogel Matrix: An Ultra-Robust Hybrid Catalyst for Enhanced Hydrogen Evolution (2022) · cites this paper as [68]
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- Authors
- Wang, Z., Li, M., Yu, J., Ge, X., Liu, Y., & Wang, W.
- Affiliations
- Chinese Academy of Sciences (CN)
- Institute of Physics Chinese Academy of Sciences Beijing 100190 China
- School of Chemistry and Chemical Engineering Southwest Petroleum University Chengdu 610500 China
- ORCID
- Liu, Yan‐Hui
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2019-12-06
- Volume
- 32
- Issue
- 4
- Pages
- e1906384-e1906384
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2991748329
- Cited by
- 138
- References
- 59
- Citations by year
- 2026: 7 · 2025: 21 · 2024: 27 · 2023: 20 · 2022: 28 · 2021: 23 · 2020: 12
- FWCI
- 3.35
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Advanced Materials (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Basic Research Program of China (2018YFA0703601)
- National Natural Science Foundation of China (11790291, 61888102)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Engineering › Mechanical Engineering › Metallic Glasses and Amorphous Alloys
- Physical Sciences › Chemistry › Inorganic Chemistry › Asymmetric Hydrogenation and Catalysis
- Keywords
- hydrogen evolution reaction, amorphous alloys, iridium-free catalysts, low iridium loading, electrocatalysis, hydrogen evolution overpotential, turnover frequency, catalyst stability, multicomponent alloys, heterogeneous catalysis
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