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The prediction of soil carbon fractions using mid-infrared-partial least square analysis
Abstract
This paper describes the application of mid-infrared (MIR) spectroscopy and partial least-squares (PLS) analysis to predict the concentration of organic carbon fractions present in soil. The PLS calibrations were derived from a standard set of soils that had been analysed for total organic carbon (TOC), particulate organic carbon (POC), and charcoal carbon (char-C) using physical and chemical means. PLS calibration models from this standard set of soils allowed the prediction of TOC, POC, and char-C fractions with a coefficient of determination (R2) of measured v. predicted data ranging between 0.97 and 0.73. For the POC fraction, the coefficient of determination could be improved (R2 = 0.94) through the use of local calibration sets. The capacity to estimate soil fractions such as char-C rapidly and inexpensively makes this approach highly attractive for studies where large numbers of analyses are required. Inclusion of a set of soils from Kenya demonstrated the robustness of the method for total organic carbon and charcoal carbon prediction.
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Cited by
Minasny, B., Malone, B. P., McBratney, A. B., Angers, D. A., Arrouays, D., Chambers, A., Chaplot, V., Chen, Z.-S., Cheng, K., Das, B. S., et al. (2017) · Geoderma · doi:10.1016/j.geoderma.2017.01.002 · Cited by 2,239
A review of biochar and its use and function in soil
Sohi, S. P., Krull, E., Lopez-Capel, E., & Bol, R. (2010) · Advances in Agronomy · doi:10.1016/s0065-2113(10)05002-9 · Cited by 2,240
Macdonald, L. M., Herrmann, T., & Baldock, J. A. (2013) · Soil Research · doi:10.1071/sr13156 · Cited by 9
Metadata
- Authors
- Janik, L. J., Skjemstad, J. O., Shepherd, K. D., & Spouncer, L. R.
- Venue
- Soil Research
- Publisher
- CSIRO Publishing
- Published
- 2007-03-28
- Volume
- 45
- Issue
- 2
- Pages
- 73-81
- ISSN
- 0004-9573 (ISSN-L)
- 1838-675X
- 1838-6768
- OpenAlex
- W2001511595
- Cited by
- 298
- References
- 0
- FWCI
- 12.62
- Type
- journal article
- Language
- en
- Open access
- closed
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- Janik, L. J., Skjemstad, J. O., Shepherd, K. D., & Spouncer, L. R. (2007). The prediction of soil carbon fractions using mid-infrared-partial least square analysis. Soil Research. https://doi.org/10.1071/sr06083
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