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Observed suppression of ozone formation at extremely high temperatures due to chemical and biophysical feedbacks
Open accessAbstract
Ground level ozone concentrations ([O 3 ]) typically show a direct linear relationship with surface air temperature. Three decades of California measurements provide evidence of a statistically significant change in the ozone-temperature slope (Δ m O3- T ) under extremely high temperatures (> 312 K). This Δ m O3- T leads to a plateau or decrease in [O 3 ], reflecting the diminished role of nitrogen oxide sequestration by peroxyacetyl nitrates and reduced biogenic isoprene emissions at high temperatures. Despite inclusion of these processes in global and regional chemistry-climate models, a statistically significant change in Δ m O3- T has not been noted in prior studies. Future climate projections suggest a more frequent and spatially widespread occurrence of this Δ m O3- T response, confounding predictions of extreme ozone events based on the historically observed linear relationship.
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Cites
Effect of climate change on air quality
Jacob, D. J., & Winner, D. A. (2009) · Atmospheric Environment · doi:10.1016/j.atmosenv.2008.09.051 · Cited by 1,979
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Fiore, A. M., Naik, V., & Leibensperger, E. M. (2015) · Journal of the Air & Waste Management Association · doi:10.1080/10962247.2015.1040526 · Cited by 537
Self-citationGlobal air quality and climate
Fiore, A. M., Naik, V., Spracklen, D. V., Steiner, A., Unger, N., Prather, M., Bergmann, D., Cameron-Smith, P. J., Cionni, I., Collins, W. J., et al. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35095e · Cited by 521
Self-citationYoung, P. J., Naik, V., Fiore, A. M., Gaudel, A., Guo, J., Lin, M. Y., Neu, J. L., Parrish, D. D., Rieder, H. E., Schnell, J. L., et al. (2018) · Elementa: Science of the Anthropocene · doi:10.1525/elementa.265 · Cited by 444
Self-citationClimate Change Penalty to Ozone Air Quality: Review of Current Understandings and Knowledge Gaps
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Climate-driven ground-level ozone extreme in the fall over the Southeast United States
Zhang, Y., & Wang, Y. (2016) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1602563113 · Cited by 132
Metadata
- Authors
- Steiner, A. L., Davis, A. J., Sillman, S., Owen, R. C., Michalak, A. M., & Fiore, A. M.
- Venue
- Proceedings of the National Academy of Sciences
- Published
- 2010-11
- Volume
- 107
- Issue
- 46
- Pages
- 19685-19690
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- OpenAlex
- W2066972914
- Cited by
- 219
- References
- 1
- FWCI
- 4.88
- Type
- journal article
- Language
- en
- Open access
- green
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- Steiner, A. L., Davis, A. J., Sillman, S., Owen, R. C., Michalak, A. M., & Fiore, A. M. (2010). Observed suppression of ozone formation at extremely high temperatures due to chemical and biophysical feedbacks. Proceedings of the National Academy of Sciences. https://doi.org/10.1073/pnas.1008336107
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