The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Edge-carboxylated graphene nanosheets via ball milling
Open accessAbstract
Low-cost, high-yield production of graphene nanosheets (GNs) is essential for practical applications. We have achieved high yield of edge-selectively carboxylated graphite (ECG) by a simple ball milling of pristine graphite in the presence of dry ice. The resultant ECG is highly dispersable in various solvents to self-exfoliate into single- and few-layer (≤ 5 layers) GNs. These stable ECG (or GN) dispersions have been used for solution processing, coupled with thermal decarboxylation, to produce large-area GN films for many potential applications ranging from electronic materials to chemical catalysts. The electrical conductivity of a thermally decarboxylated ECG film was found to be as high as 1214 S/cm, which is superior to its GO counterparts. Ball milling can thus provide simple, but efficient and versatile, and eco-friendly (CO 2 -capturing) approaches to low-cost mass production of high-quality GNs for applications where GOs have been exploited and beyond.
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Cites
Electric Field Effect in Atomically Thin Carbon Films
Novoselov, K. S., Geim, A. K., Morozov, S. V., Jiang, D., Zhang, Y., Dubonos, S. V., Grigorieva, I. V., & Firsov, A. A. (2004) · Science · doi:10.1126/science.1102896 · Cited by 66,834
Geim, A. K., & Novoselov, K. S. (2007) · Nature Materials · doi:10.1038/nmat1849 · Cited by 39,979
The chemistry of graphene oxide
Dreyer, D. R., Park, S., Bielawski, C. W., & Ruoff, R. S. (2010) · Chem. Soc. Rev. · doi:10.1039/b917103g · Cited by 11,653
Cited by
Metal-Free Catalysts for Oxygen Reduction Reaction
Dai, L., Xue, Y., Qu, L., Choi, H.-J., & Baek, J.-B. (2015) · Chemical Reviews · doi:10.1021/cr5003563 · Cited by 2,380
Self-citationCarbon-based electrocatalysts for advanced energy conversion and storage
Zhang, J., Xia, Z., & Dai, L. (2015) · Science Advances · doi:10.1126/sciadv.1500564 · Cited by 735
Self-citationBrisebois, P. P., & Siaj, M. (2020) · Journal of Materials Chemistry C · doi:10.1039/c9tc03251g · Cited by 445
Recent advances in ruthenium-based electrocatalysts for the hydrogen evolution reaction
Bae, S.-Y., Mahmood, J., Jeon, I.-Y., & Baek, J.-B. (2020) · Nanoscale Horizons · doi:10.1039/c9nh00485h · Cited by 334
Self-citationFeng, Z.-Q., Yuan, X., & Wang, T. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.123730 · Cited by 113
Metadata
- Authors
- Jeon, I.-Y., Shin, Y.-R., Sohn, G.-J., Choi, H.-J., Bae, S.-Y., Mahmood, J., Jung, S.-M., Seo, J.-M., Kim, M.-J., Wook Chang, D., Dai, L., & Baek, J.-B.
- Venue
- Proceedings of the National Academy of Sciences
- Published
- 2012-03-27
- Volume
- 109
- Issue
- 15
- Pages
- 5588-5593
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- OpenAlex
- W2061475115
- Cited by
- 685
- References
- 3
- FWCI
- 21.00
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Jeon, I.-Y., Shin, Y.-R., Sohn, G.-J., Choi, H.-J., Bae, S.-Y., Mahmood, J., Jung, S.-M., Seo, J.-M., Kim, M.-J., Wook Chang, D., Dai, L., & Baek, J.-B. (2012). Edge-carboxylated graphene nanosheets via ball milling. Proceedings of the National Academy of Sciences. https://doi.org/10.1073/pnas.1116897109
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