The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Rapid self-assembly of brush block copolymers to photonic crystals
Open accessAbstract
The reduced chain entanglement of brush polymers over their linear analogs drastically lowers the energetic barriers to reorganization. In this report, we demonstrate the rapid self-assembly of brush block copolymers to nanostructures with photonic bandgaps spanning the entire visible spectrum, from ultraviolet (UV) to near infrared (NIR). Linear relationships were observed between the peak wavelengths of reflection and polymer molecular weights. This work enables “bottom-up” fabrication of photonic crystals with application-tailored bandgaps, through synthetic control of the polymer molecular weight and the method of self-assembly. These polymers could be developed into NIR-reflective paints, to combat the “urban heat island effect” due to NIR photon thermalization.
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Cites
Multiblock Polymers: Panacea or Pandora’s Box?
Bates, F. S., Hillmyer, M. A., Lodge, T. P., Bates, C. M., Delaney, K. T., & Fredrickson, G. H. (2012) · Science · doi:10.1126/science.1215368 · Cited by 1,147
Ordered Nanoporous Polymers from Polystyrene−Polylactide Block Copolymers
Zalusky, A. S., Olayo-Valles, R., Wolf, J. H., & Hillmyer, M. A. (2002) · Journal of the American Chemical Society · doi:10.1021/ja0278584 · Cited by 553
Cited by
50th Anniversary Perspective: Block Polymers—Pure Potential
Bates, C. M., & Bates, F. S. (2017) · Macromolecules · doi:10.1021/acs.macromol.6b02355 · Cited by 788
Shieh, P., Nguyen, H. V.-T., & Johnson, J. A. (2019) · Nature Chemistry · doi:10.1038/s41557-019-0352-4 · Cited by 233
Metadata
- Authors
- Sveinbjörnsson, B. R., Weitekamp, R. A., Miyake, G. M., Xia, Y., Atwater, H. A., & Grubbs, R. H.
- Venue
- Proceedings of the National Academy of Sciences
- Published
- 2012-08-21
- Volume
- 109
- Issue
- 36
- Pages
- 14332-14336
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- OpenAlex
- W4235024652
- Cited by
- 413
- References
- 2
- FWCI
- 8.64
- Type
- journal article
- Language
- en
- Open access
- green
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- Sveinbjörnsson, B. R., Weitekamp, R. A., Miyake, G. M., Xia, Y., Atwater, H. A., & Grubbs, R. H. (2012). Rapid self-assembly of brush block copolymers to photonic crystals. Proceedings of the National Academy of Sciences. https://doi.org/10.1073/pnas.1213055109
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