Multiblock Polymers: Panacea or Pandora’s Box?
Abstract
Getting Around the Block: Diblock copolymers provide a rich variety of morphologies that depend on the length of the polymer blocks, the overall fraction of each block, and their chemical dissimilarity. New synthetic methods have made it possible to make copolymers with three or more components and in a range of chemical architectures. However, this growth in design choices can offer too many variables to work with, and rational design is important, especially when trying to transform small-scale products in engineered commodities. Bates et al. (p. 434) review the opportunities and complexities that exist when working in this expanded playground of block copolymers.
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The ability to synthesize multiblock polymers remains a challenge most commonly met through tedious sequential monomer additions.
“the ability to synthesize multiblock polymers remains a challenge most commonly met through tedious sequential monomer additions”
From Chemically recyclable polyolefin-like multiblock polymers (2023) · cites this paper as [33]
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- Authors
- Bates, F. S., Hillmyer, M. A., Lodge, T. P., Bates, C. M., Delaney, K. T., & Fredrickson, G. H.
- Affiliations
- University of Minnesota (US)
- The University of Texas at Austin (US)
- University of California, Santa Barbara (US)
- Corresponding author
- Bates, Frank S.
- ORCID
- Venue
- Science
- Published
- 2012-04-27
- Volume
- 336
- Issue
- 6080
- Pages
- 434-440
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2019912098
- Cited by
- 1,147
- References
- 50
- Citations by year
- 2026: 51 · 2025: 78 · 2024: 89 · 2023: 85 · 2022: 68 · 2021: 87 · 2020: 83 · 2019: 91 · 2018: 85 · 2017: 93 · 2016: 109 · 2015: 76 · 2014: 70 · 2013: 59 · 2012: 23
- FWCI
- 33.55
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Science (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Keywords
- multiblock copolymers, block copolymers, triblock copolymers, polymer self-assembly, molecular architecture, polymer synthesis
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