Tuning friction to a superlubric state via in-plane straining
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Controlling, and in many cases minimizing, friction is a goal that has long been pursued in history. From the classic Amontons–Coulomb law to the recent nanoscale experiments, the steady-state friction is found to be an inherent property of a sliding interface, which typically cannot be altered on demand. In this work, we show that the friction on a graphene sheet can be tuned reversibly by simple mechanical straining. In particular, by applying a tensile strain (up to 0.60%), we are able to achieve a superlubric state (coefficient of friction nearly 0.001) on a suspended graphene. Our atomistic simulations together with atomically resolved friction images reveal that the in-plane strain effectively modulates the flexibility of graphene. Consequently, the local pinning capability of the contact interface is changed, resulting in the unusual strain-dependent frictional behavior. This work demonstrates that the deformability of atomic-scale structures can provide an additional channel of regulating the friction of contact interfaces involving configurationally flexible materials.
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Cites
Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene
Lee, C., Wei, X., Kysar, J. W., & Hone, J. (2008) · Science · doi:10.1126/science.1157996 · Cited by 21,100 · see citing works
The Friction and Lubrication of Solids
Bowden, F. P., Tabor, D., & Palmer, F. (1951) · American Journal of Physics · doi:10.1119/1.1933017 · Cited by 5,986 · see citing works
Impermeable Atomic Membranes from Graphene Sheets
Bunch, J. S., Verbridge, S. S., Alden, J. S., van der Zande, A. M., Parpia, J. M., Craighead, H. G., & McEuen, P. L. (2008) · Nano Letters · doi:10.1021/nl801457b · Cited by 2,929 · see citing works
Frictional Characteristics of Atomically Thin Sheets
Lee, C., Li, Q., Kalb, W., Liu, X.-Z., Berger, H., Carpick, R. W., & Hone, J. (2010) · Science · doi:10.1126/science.1184167 · Cited by 1,818 · see citing works
Self-citationAtomic Structure of Graphene on SiO2
Ishigami, M., Chen, J., Cullen, W. G., Fuhrer, M. S., & Williams, E. D. (2007) · Nano Letters · doi:10.1021/nl070613a · Cited by 1,526 · see citing works
Dienwiebel, M., Verhoeven, G. S., Namboodiri, P. N., Frenken, J. W. M., Heimberg, J. A., & Zandbergen, H. W. (2004) · Physical Review Letters · doi:10.1103/physrevlett.92.126101 · Cited by 1,435 · see citing works
Atomic Structure of Graphene on SiO2
Williams, E. D. (2007) · Cited by 1,145 · see citing works
Scratching the Surface: Fundamental Investigations of Tribology with Atomic Force Microscopy
Carpick, R. W., & Salmerón, M. (1997) · Chemical Reviews · doi:10.1021/cr960068q · Cited by 1,128 · see citing works
Ultrastrong adhesion of graphene membranes
Koenig, S. P., Boddeti, N. G., Dunn, M. L., & Bunch, J. S. (2011) · Nature Nanotechnology · doi:10.1038/nnano.2011.123 · Cited by 1,107 · see citing works
Friction laws at the nanoscale
Mo, Y., Turner, K. T., & Szlufarska, I. (2009) · Nature · doi:10.1038/nature07748 · Cited by 939 · see citing works
Socoliuc, A., Bennewitz, R., Gnecco, E., et al. (2004) · Physical Review Letters · doi:10.1103/physrevlett.92.134301 · Cited by 600 · see citing works
Observation of Microscale Superlubricity in Graphite
Liu, Z., Yang, J., Grey, F., Liu, J. Z., Liu, Y., Wang, Y., Yang, Y., Cheng, Y., & Zheng, Q. (2012) · Physical Review Letters · doi:10.1103/physrevlett.108.205503 · Cited by 586 · see citing works
Friction and Dissipation in Epitaxial Graphene Films
Filleter, T., McChesney, J. L., Bostwick, A., Rotenberg, E., Emtsev, K. V., Seyller, T. K., Horn, K., & Bennewitz, R. (2009) · Physical Review Letters · doi:10.1103/physrevlett.102.086102 · Cited by 576 · see citing works
Colloquium : Modeling friction: From nanoscale to mesoscale
Vanossi, A., Manini, N., Urbakh, M., Zapperi, S., & Tosatti, E. (2013) · Reviews of Modern Physics · doi:10.1103/revmodphys.85.529 · Cited by 548 · see citing works
The evolving quality of frictional contact with graphene
Li, S., Li, Q., Carpick, R. W., Gumbsch, P., Liu, X. Z., Ding, X., Sun, J., & Li, J. (2016) · Nature · doi:10.1038/nature20135 · Cited by 541 · see citing works
Self-citationRaman Spectroscopy of Graphene and Bilayer under Biaxial Strain: Bubbles and Balloons
Jakob, Z., Nair, R. R., Ott, A. K., Georgiou, T., Geim, A. K., Novoselov, K. S., & Casiraghi, C. (2011) · Nano Letters · doi:10.1021/nl203359n · Cited by 519 · see citing works
Recent advances in single-asperity nanotribology
Szlufarska, I., Chandross, M., & Carpick, R. W. (2008) · Journal of Physics D Applied Physics · doi:10.1088/0022-3727/41/12/123001 · Cited by 472 · see citing works
The friction and lubrication of solids
Kobe, K. A. (1951) · Journal of Chemical Education · doi:10.1021/ed028p230.3 · Cited by 465 · see citing works
Tribology of two-dimensional materials: From mechanisms to modulating strategies
Zhang, S., Ma, T., Erdemir, A., & Li, Q. (2019) · Materials Today · doi:10.1016/j.mattod.2018.12.002 · Cited by 407 · see citing works
Self-citationFriction Anisotropy–Driven Domain Imaging on Exfoliated Monolayer Graphene
Choi, J. S., Kim, J.-S., Byun, I.-S., Lee, D. H., Lee, M. J., Park, B. H., Lee, C., Yoon, D., Cheong, H., Lee, K., et al. (2011) · Science · doi:10.1126/science.1207110 · Cited by 330 · see citing works
Simple Microscopic Theory of Amontons's Laws for Static Friction
Müser, M. H., Wenning, L., & Robbins, M. O. (2001) · Physical Review Letters · doi:10.1103/physrevlett.86.1295 · Cited by 309 · see citing works
Adhesion-dependent negative friction coefficient on chemically modified graphite at the nanoscale
Deng, Z., Smolyanitsky, A., Li, Q., Feng, X., & Cannara, R. J. (2012) · Nature Materials · doi:10.1038/nmat3452 · Cited by 304 · see citing works
Self-citationMeasuring Interlayer Shear Stress in Bilayer Graphene
Wang, G., Dai, Z., Wang, Y., Tan, P., Liu, L., Xu, Z., Wei, Y., Huang, R., & Zhang, Z. (2017) · Physical Review Letters · doi:10.1103/physrevlett.119.036101 · Cited by 270 · see citing works
Self-citationSpatially resolved spectroscopy of monolayer graphene on SiO2
Deshpande, A., Bao, W., Miao, F., et al. (2009) · Physical Review B · doi:10.1103/physrevb.79.205411 · Cited by 249 · see citing works
Tribology on the small scale: a bottom up approach to friction, lubrication, and wear
(2008) · Choice Reviews Online · doi:10.5860/choice.46-0902 · Cited by 230 · see citing works
Scaling Laws of Structural Lubricity
Dietzel, D., Feldmann, M., Schwarz, U. D., Fuchs, H., & Schirmeisen, A. (2013) · Physical Review Letters · doi:10.1103/physrevlett.111.235502 · Cited by 182 · see citing works
Thickness-Dependent Hydrophobicity of Epitaxial Graphene
Munz, M., Giusca, C. E., Myers‐Ward, R. L., et al. (2015) · ACS Nano · doi:10.1021/acsnano.5b03220 · Cited by 159 · see citing works
Urbakh, M., & Meyer, E. (2009) · Nature Materials · doi:10.1038/nmat2599 · Cited by 148 · see citing works
Nanoscale Friction Varied by Isotopic Shifting of Surface Vibrational Frequencies
Cannara, R. J., Brukman, M. J., Cimatu, K. L. A., et al. (2007) · Science · doi:10.1126/science.1147550 · Cited by 145 · see citing works
Structural lubricity under ambient conditions
Cihan, E., İpek, S., Durgun, E., et al. (2016) · Nature Communications · doi:10.1038/ncomms12055 · Cited by 138 · see citing works
Deng, Z., Klimov, N. N., Solares, S. D. J., Li, T., Xu, H., & Cannara, R. J. (2012) · Langmuir · doi:10.1021/la304079a · Cited by 128 · see citing works
Kitt, A. L., Qi, Z., Rémi, S., Park, H. S., Swan, A. K., & Goldberg, B. B. (2013) · Nano Letters · doi:10.1021/nl4007112 · Cited by 111 · see citing works
Efficient and Robust Fabrication of Microscale Graphene Drums
Yin, P., & Ma, M. D. (2018) · ACS Applied Nano Materials · doi:10.1021/acsanm.8b01347 · Cited by 16 · see citing works
Theoretical Studies of Superlubricity
Müser, M. H. (2014) · Nanoscience and technology · doi:10.1007/978-3-319-10560-4_11 · Cited by 13 · see citing works
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Research works printed but not linked: 1
- [3]3. C. M. Mate, Tribology on the Small Scale (Oxford University Press, New York, 2008).
Cited by
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Probing the hydration friction of ionic interfaces at the atomic scale
Li, Z., Liu, Q., Zhang, D., Wang, Y., Zhang, Y., Li, Q., & Dong, M. (2022) · Nanoscale Horizons · doi:10.1039/d1nh00564b · Cited by 30 · see citing works
Self-citation
- Authors
- Zhang, S., Hou, Y., Li, S., Liu, L., Zhang, Z., Feng, X.-Q., & Li, Q.
- Affiliations
- State Key Laboratory of Tribology (CN)
- University of Science and Technology of China (CN)
- Xi'an Jiaotong University (CN)
- Chinese Academy of Sciences (CN)
- Corresponding author
- Li, Qunyang
- Venue
- Proceedings of the National Academy of Sciences
- Publisher
- National Academy of Sciences
- Published
- 2019-10-28
- Volume
- 116
- Issue
- 49
- Pages
- 24452-24456
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- PMC
- PMC6900536
- OpenAlex
- W2982706077
- Cited by
- 138
- References
- 34
- Citations by year
- 2026: 16 · 2025: 26 · 2024: 22 · 2023: 20 · 2022: 27 · 2021: 17 · 2020: 9 · 2019: 1
- FWCI
- 5.95
- Type
- journal article
- Language
- en
- Update notices
- correction (2020-03-16)
- Open access
- bronze
- doi.org
- Locations
- Proceedings of the National Academy of Sciences (publishedVersion)
- PubMed Central (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Natural Science Foundation of China (11772169, 11432008, 11832010, 11890682, 11890671)
- ational Basic Research Program of China (2015CB351903)
- National Science and Technology Major Project (2017-VI-0003-0073)
- State Key Laboratory of Tribology at Tsinghua University (SKLT2019B02)
- Topics
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Force Microscopy Techniques and Applications
- Physical Sciences › Engineering › Mechanics of Materials › Adhesion, Friction, and Surface Interactions
- Physical Sciences › Materials Science › Materials Chemistry › Graphene research and applications
- Keywords
- superlubricity, graphene, in-plane strain, tensile strain, suspended graphene, atomic-scale friction, deformable materials, atomistic simulation
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