The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Self-recognition in helicate self-assembly: spontaneous formation of helical metal complexes from mixtures of ligands and metal ions.
Open accessAbstract
On treatment with copper(I) ions, mixtures of the [oligo(2,2')-bipyridine] strands 2-5 yield spontaneously the double helicates 2H(2)-2H(5) without significant crossover. Similarly, when a mixture of the two tris-bypyridine ligands 1 and 3a (containing different substitutions) is allowed to react with copper(I) and nickel(II) ions, only the double helicate 2H(3a) and the triple helicate 3H(1) are formed. Thus, these systems undergo self-assembly of helicates with self-recognition. The process represents a self/nonself-discrimination involving the preferential binding of like metal ions by like ligand strands in a mixture to selectively assemble into the corresponding helicates. In a broader perspective, these results point to a change in paradigm from pure compounds to instructed mixtures--that is from seeking chemical purity to designing programmed systems composed of mixtures of instructed components capable of spontaneously forming well--defined superstructures through self-processes.
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Cites
Encoded combinatorial chemistry.
Brenner, S., & Lerner, R. A. (1992) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.89.12.5381 · Cited by 1,014
Lehn, J. M., Rigault, A., Siegel, J., Harrowfield, J., Chevrier, B., & Moras, D. (1987) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.84.9.2565 · Cited by 852
Self-citation
Cited by
Self‐Assembly in Natural and Unnatural Systems
Philp, D., & Stoddart, J. F. (1996) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199611541 · Cited by 2,115
Yashima, E., Ousaka, N., Taura, D., Shimomura, K., Ikai, T., & Maeda, K. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00354 · Cited by 2,004
Beuerle, F., & Gole, B. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201710190 · Cited by 528
Selbstorganisation in natürlichen und in nichtnatürlichen Systemen
Philp, D., & Stoddart, J. F. (1996) · Angewandte Chemie · doi:10.1002/ange.19961081105 · Cited by 466
Functional behaviour from controlled self-assembly: challenges and prospects
Ward, M. D., & Raithby, P. R. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35123d · Cited by 444
Metadata
- Authors
- Kramer, R., Lehn, J. M., & Marquis-Rigault, A.
- Venue
- Proceedings of the National Academy of Sciences
- Published
- 1993-06-15
- Volume
- 90
- Issue
- 12
- Pages
- 5394-5398
- ISSN
- 0027-8424 (ISSN-L)
- 1091-6490
- OpenAlex
- W2091383063
- Cited by
- 549
- References
- 2
- FWCI
- 8.49
- Type
- journal article
- Language
- en
- Open access
- green
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- Kramer, R., Lehn, J. M., & Marquis-Rigault, A. (1993). Self-recognition in helicate self-assembly: spontaneous formation of helical metal complexes from mixtures of ligands and metal ions. Proceedings of the National Academy of Sciences. https://doi.org/10.1073/pnas.90.12.5394
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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