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Reaction Mechanism of Fluoroacetate Dehalogenase from Moraxella sp. B
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“The latter was subsequently hydrolyzed by a water molecule activated by His-272 (71).”
From Toward the development of a molecular toolkit for the microbial remediation of per-and polyfluoroalkyl substances (2024) · cites this paper as [71]
In the citing paper
“The catalytic mechanism for hydrolysis of fluoroacetate by haloacid dehalogenases is an SN2 displacement reaction involving two steps, namely, the formation of an enzyme-ester intermediate followed by the subsequent hydrolysis of the ester intermediate via an activated water molecule (71, 77) (Fig. 2).”
From Toward the development of a molecular toolkit for the microbial remediation of per-and polyfluoroalkyl substances (2024) · cites this paper as [71]
In the citing paper
“Site-directed mutagenesis and molecular simulations demonstrated the essential role of aspartate (Asp-105; H-1 numbering) and histidine (His-272; H-1 numbering) in the catalytic process.”
From Toward the development of a molecular toolkit for the microbial remediation of per-and polyfluoroalkyl substances (2024) · cites this paper as [71]
In the citing paper
“Asp-105 serves as a nucleophile to attack the α-carbon of fluoroacetate, leading to the release of a fluoride anion and the formation of an enzyme-ester intermediate.”
From Toward the development of a molecular toolkit for the microbial remediation of per-and polyfluoroalkyl substances (2024) · cites this paper as [71]
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Mapping the reaction coordinates of enzymatic defluorination
Chan, P. W. Y., Yakunin, A. F., Edwards, E. A., & Pai, E. F. (2011) · Journal of the American Chemical Society · doi:10.1021/ja200277d · Cited by 107
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Murphy, C. D. (2010) · Biotechnology Letters · doi:10.1007/s10529-009-0174-3 · Cited by 93
Hu, M., & Scott, C. (2024) · Applied and Environmental Microbiology · doi:10.1128/aem.00157-24 · Cited by 63
Dodge, A. G., Thoma, C. J., O’Connor, M. R., & Wackett, L. P. (2024) · mBio · doi:10.1128/mbio.02785-23 · Cited by 23
Metadata
- Authors
- Liu, J.-Q., Kurihara, T., Ichiyama, S., Miyagi, M., Tsunasawa, S., Kawasaki, H., Soda, K., & Esaki, N.
- Venue
- Journal of Biological Chemistry
- Publisher
- Elsevier BV
- Published
- 1998-11
- Volume
- 273
- Issue
- 47
- Pages
- 30897-30902
- ISSN
- 0021-9258
- Cited by
- 88
- References
- 0
- Language
- en
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Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
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