Influence of Crystallization Process on Structural State of CSD BST Thin Films
Abstract
The effect of a thin seeding layer (about 30 nm) on crystallization behavior of CSD BST film is studied. The seeding layer is prepared from alkoxide precursor and annealed at different temperatures. The main BST film is deposited from alkoxide solution modified by 2-ethylhexanoic acid. It is shown that the increase of annealing temperature of the seeding layer from 500 to 700°C changes crystalline structure of upper deposited layer from a randomly oriented polycrystalline to an oriented columnar grain.
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The main strategy of columnar grain growth in CSD films is a choice of the substrate with a close lattice constant or introducing an intermediate seeding layer whose structure decreases the Gibbs free energy ΔGv at the interface.
“For this reason, the main strategy of columnar grain growth in CSD films is a choice of the substrate with a close lattice constant or introducing an intermediate seeding layer whose structure decreases the Gibbs free energy ΔGv at the interface [32,46,47].”
From Control of Columnar Grain Microstructure in CSD LaNiO3 Films (2023) · cites this paper as [47]
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Control of Columnar Grain Microstructure in CSD LaNiO3 Films
Atanova, A. V., Seregin, D. S., Zhigalina, O. M., Khmelenin, D. N., Orlov, G. A., Turkina, D. I., Sigov, A. S., & Vorotilov, K. A. (2023) · Molecules · doi:10.3390/molecules28041938 · Cited by 5 · see citing works
Self-citation
- Authors
- Zhigalina, O. M., Vorotilov, K. A., Sigov, A. S., & Kumskov, A. S.
- Affiliations
- Russian Academy of Sciences (RU)
- MIREA - Russian Technological University (RU)
- Venue
- Ferroelectrics
- Publisher
- Informa UK Limited
- Published
- 2006-07
- Volume
- 335
- Issue
- 1
- Pages
- 13-21
- ISSN
- 0015-0193 (ISSN-L)
- 1563-5112
- OpenAlex
- W2035139461
- Cited by
- 8
- References
- 0
- Citations by year
- 2023: 1 · 2021: 1 · 2017: 1 · 2016: 1 · 2012: 1
- FWCI
- 0.66
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Ferroelectrics (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Ferroelectric and Piezoelectric Materials
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Multiferroics and related materials
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Microwave Dielectric Ceramics Synthesis
- Keywords
- barium strontium titanate, crystallization, seed layer, annealing temperature, alkoxide precursors, 2-ethylhexanoic acid, columnar grains, grain orientation, ferroelectric thin films
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