Recent Studies on the Formation and Properties of Quinhydrone Complexes
Abstract
Several aspects of the strusctural and solid state chemistry of quicnhydrones are described. Among the topics discussed are the preparation of isomeric quicnhydrones, involving a solid state synthesis by grinding the components together, mothods of interconversion of isomeric quinhydrones, and the use of spectroscopic methods including 13C nmr to follow the interconversion. The important features of the crystal structures of several key complexes of quinones and hydroquinones are also descsribed. Some rationalizations for the differences in ease of formation and in stoichiometry of complexes involving methyl substitutents are also presentes.
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The second model is the "noncovalent bonding (quinhydrones)" polymerization fashion where DA monomers are linked together by noncovalent interaction including hydrogen bonding, charge transfer, ionic interaction, and π-stacking to aggregate into a structural macroassembly.
“The second model is the “noncovalent bonding (quinhydrones)” polymerization fashion where DA monomers are linked together by noncovalent interaction including hydrogen bonding, charge transfer, ionic interaction, and π-stacking to aggregate into a structural macroassembly [35, 45–47].”
From Polydopamine-Assisted Surface Modification for Bone Biosubstitutes (2016) · cites this paper as [46]
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Polydopamine-Assisted Surface Modification for Bone Biosubstitutes
Huang, S., Liang, N., Hu, Y., Zhou, X., & Abidi, N. (2016) · BioMed Research International · doi:10.1155/2016/2389895 · Cited by 97 · see citing works
“The second model is the “noncovalent bonding (quinhydrones)” polymerization fashion where DA monomers are linked together by noncovalent interaction including hydrogen bonding, charge transfer, ionic interaction, and πstacking to aggregate into a structural macroassembly [35, 45–47].”
Background
- Authors
- Patil, A. O., Pennington, W. T., Desiraju, G. R., Curtin, D. Y., & Paul, I. C.
- Affiliations
- University of Illinois Urbana-Champaign (US)
- Venue
- Molecular Crystals and Liquid Crystals
- Publisher
- Informa UK Limited
- Published
- 1986-04
- Volume
- 134
- Issue
- 1
- Pages
- 279-304
- ISSN
- 0026-8941 (ISSN-L)
- OpenAlex
- W2010071927
- Cited by
- 25
- References
- 0
- Citations by year
- 2026: 2 · 2025: 1 · 2024: 1 · 2022: 1 · 2021: 1 · 2020: 1 · 2019: 1 · 2018: 1 · 2017: 1 · 2016: 3 · 2014: 1 · 2013: 4 · 2012: 1
- FWCI
- 0.33
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Molecular crystals and liquid crystals (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Liquid Crystal Research Advancements
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Crystallography and molecular interactions
- Physical Sciences › Chemistry › Organic Chemistry › Supramolecular Chemistry and Complexes
- Keywords
- crystal structure, 13C NMR, methyl substituent effects, complex stoichiometry
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