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Statistical thermodynamics of convex molecule fluids
Abstract
A theoretical study of the statistical mechanical description of systems composed of non-spherical convex molecules is made. Thermodynamic functions of one-component and multicomponent systems of particles interacting via the pair potential of the Kihara core type are expressed by integrals over the minimum distance between two interacting convex bodies and three angles characterizing the convex body geometry. The approach is applied to the hard convex body system where the averaged contact correlation function is introduced. Exploiting ideas of the scaled particle theory the approximate expressions for the averaged correlation functions are given in terms of the geometric functionals of hard convex bodies.
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Citations
Cited by
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Barker, J. A., & Henderson, D. (1976) · Reviews of Modern Physics · doi:10.1103/revmodphys.48.587 · Cited by 2,104
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Ellis, R. J., & Minton, A. P. (2006) · Biological Chemistry · doi:10.1515/bc.2006.064 · Cited by 421
Allen, M. P., Evans, G. T., Frenkel, D., & Mulder, B. M. (1993) · Advances in Chemical Physics · doi:10.1002/9780470141458.ch1 · Cited by 332
Metadata
- Authors
- Boublík, T.
- Venue
- Molecular Physics
- Publisher
- Informa UK Limited
- Published
- 1974-05
- Volume
- 27
- Issue
- 5
- Pages
- 1415-1427
- ISSN
- 0026-8976 (ISSN-L)
- 1362-3028
- OpenAlex
- W2094501734
- Cited by
- 209
- References
- 0
- FWCI
- 5.94
- Type
- journal article
- Language
- en
- Open access
- closed
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- Boublík, T. (1974). Statistical thermodynamics of convex molecule fluids. Molecular Physics. https://doi.org/10.1080/00268977400101191
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