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Cited by 1,205

The DOI matches its Crossref record; 13 of the 13 references it cites were found in a registry or an index.

Phase equilibria of associating fluids: Chain molecules with multiple bonding sites

Chapman, Walter G., Jackson, George, Gubbins, Keith E.·1988·Molecular Physics
DOI 10.1080/00268978800101601
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Abstract

As a continuation of our work on spherical associating molecules, we have derived expressions for changes in the thermodynamic properties due to association in mixtures of molecules with multiple bonding sites. The equations are written in terms of a hard-core reference whose pair distribution function is known. In practise, the hard-sphere reference mixture is the easiest to use. A reference system of homonuclear chains is examined in order to account for asymmetries in molecular shape; chains are constructed by bonding equal-sized spheres together. An equation of state for hard-sphere chains is obtained which is in good agreement with recent simulation data. Expressions for mixtures of homonuclear chains of different sizes are also presented. The approach is extended to examine associating chain molecules with multiple bonding sites. The phase equilibria of non-associating chains, and of associating chains with one or two bonding sites are determined. In this study, the separate effects of molecular association and chain size on the coexistence properties are investigated.

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Metadata

Authors
Chapman, W. G., Jackson, G., & Gubbins, K. E.
Venue
Molecular Physics
Publisher
Informa UK Limited
Published
1988-12-10
Volume
65
Issue
5
Pages
1057-1079
ISSN
  • 0026-8976 (ISSN-L)
  • 1362-3028
DOI
10.1080/00268978800101601
OpenAlex
W1526287499
Cited by
1,205
References
13
FWCI
7.96
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Phase equilibria of associating fluids: Chain molecules with multiple bonding sites. https://app.cochat.ai/papers/10.1080/00268978800101601
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Chapman, W. G., Jackson, G., & Gubbins, K. E. (1988). Phase equilibria of associating fluids: Chain molecules with multiple bonding sites. Molecular Physics. https://doi.org/10.1080/00268978800101601

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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