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DISCRETE- vs. CONTINUOUS-TIME NONLINEAR SIGNAL PROCESSING OF Cu ELECTRODISSOLUTION DATA
Abstract
Artificial neural networks (ANNs) are often used for short term discrete time predictions of experimental data. In this paper we focus on the capability of such nets to correctly identify long term behavior and, in particular, observed bifurcations. As we show, the usual discrete time mapping approach is (precisely because of its discrete nature) often incapable of reproducing observed bifurcation sequences. If the interest is only in periodic or temporally more complicated behavior, a Poincaré map extracted from the experimental time series can be used to circumvent this problem. A complete dynamic picture including bifurcations of steady states can, however, only be captured by a continuous-time model. We present an ANN configuration which couples a “nonlinear principal component” network for data processing (Kramer, 1991, Usui et al., 1990) with a composite ANN based on a simple integrator scheme. This ANN is able to correctly reconstruct the bifurcation diagram of our experimental data. All time series we process stem from the potentiostatic electrodissolution of Cu in phosphoric acid solution. As the applied potential is varied, the electrodissolution rate changes from steady behavior to periodic oscillations, followed by a sequence of period doublings to apparently chaotic motion, and then returns to simple oscillations via a reverse cascade of period doublings.
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“Indeed, hybrid modeling techniques and applications have been growing in number since the early 90's (Psichogios and Ungar 1992; Rico-Martínez et al. 1992; Thompson and Kramer 1994)”
From Perspectives on the integration between first-principles and data-driven modeling (2022) · cites this paper as Rico-Martínez et al. 1992
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Cites
Nonlinear Oscillations, Dynamical Systems, and Bifurcations of Vector Fields
Guckenheimer, J., & Holmes, P. (1983) · Applied Mathematical Sciences · doi:10.1007/978-1-4612-1140-2 · Cited by 16,144
Parallel Distributed Processing: Explorations in the Microstructure of Cognition: Foundations
Rumelhart, D. E., McClelland, J. L., & AU (1986) · doi:10.7551/mitpress/5236.001.0001 · Cited by 15,686
Approximation by superpositions of a sigmoidal function
Cybenko, G. (1989) · Mathematics of Control, Signals, and Systems · doi:10.1007/bf02551274 · Cited by 13,883
Detecting strange attractors in turbulence
Takens, F. (1981) · Lecture Notes in Mathematics · doi:10.1007/bfb0091924 · Cited by 10,459
Independent coordinates for strange attractors from mutual information
Fraser, A. M., & Swinney, H. L. (1986) · Physical Review A · doi:10.1103/physreva.33.1134 · Cited by 4,665
Packard, N. H., Crutchfield, J. P., Farmer, J. D., & Shaw, R. S. (1980) · Physical Review Letters · doi:10.1103/physrevlett.45.712 · Cited by 3,909
Nonlinear principal component analysis using autoassociative neural networks
Kramer, M. A. (1991) · AIChE Journal · doi:10.1002/aic.690370209 · Cited by 3,037
Simplified neuron model as a principal component analyzer
Oja, E. (1982) · Journal of Mathematical Biology · doi:10.1007/bf00275687 · Cited by 2,309
Extracting qualitative dynamics from experimental data
Broomhead, D. S., & King, G. P. (1986) · Physica D Nonlinear Phenomena · doi:10.1016/0167-2789(86)90031-x · Cited by 2,289
Theory of the backpropagation neural network
Hecht-Nielsen (1989) · International Joint Conference on Neural Networks (IJCNN) · doi:10.1109/ijcnn.1989.118638 · Cited by 2,274
Research works printed but not linked: 5
- Bayly B., 1987, J. Sci. Cornp., 2, 111
- Doedel E.J., 1981, Cong. Num., 30, 265
- Hecht-Nielsen R., 1989, Proc. Intl. Joint Conf. Neural Networks
- Lapedes A.S., 1987, Los Alamos Report LA-UR, 87
- Usui S., 1990, Proceedings 1990 IEEE INNS IJCNN, 2, 515
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Metadata
- Authors
- RICO-MARTÍNEZ, R., KRISCHER, K., KEVREKIDIS, I. G., KUBE, M. C., & HUDSON, J. L.
- Affiliations
- a Department of Chemical Engineering , Princeton University , Princeton, NJ, 08544-5263
- Princeton University (US)
- University of Virginia (US)
- Venue
- Chemical Engineering Communications
- Publisher
- Informa UK Limited
- Published
- 1992-11
- Volume
- 118
- Issue
- 1
- Pages
- 25-48
- ISSN
- 0098-6445 (ISSN-L)
- 1563-5201
- OpenAlex
- W1976068300
- Cited by
- 144
- References
- 41
- Citations by year
- 2026: 4 · 2025: 16 · 2024: 20 · 2023: 18 · 2022: 11 · 2021: 10 · 2020: 6 · 2019: 7 · 2018: 5 · 2015: 1
- FWCI
- 3.12
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Engineering Communications (publishedVersion)
- Funders
- David and Lucile Packard Foundation
- Deutsche Forschungsgemeinschaft
- Defense Advanced Research Projects Agency
- Topics
- Physical Sciences › Computer Science › Artificial Intelligence › Neural Networks and Applications
- Physical Sciences › Physics and Astronomy › Statistical and Nonlinear Physics › Chaos control and synchronization
- Physical Sciences › Physics and Astronomy › Statistical and Nonlinear Physics › Nonlinear Dynamics and Pattern Formation
- Keywords
- bifurcation diagrams, period doubling, Poincaré map, continuous-time neural networks, artificial neural networks, chaotic oscillations, periodic oscillations, phosphoric acid solutions, potentiostatic measurements, nonlinear signal processing
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