The DOI matches its Crossref record; 31 of the 31 references it cites were found in a registry or an index.
The physical chemistry of Criegee intermediates in the gas phase
Open accessAbstract
Carbonyl oxides, also known as Criegee intermediates, are key intermediates in both gas phase ozonolysis of unsaturated hydrocarbons in the troposphere and solution phase organic synthesis via ozonolysis. Although the study of Criegee intermediates in both arenas has a long history, direct studies in the gas phase have only recently become possible through new methods of generating stabilised Criegee intermediates in sufficient quantities. This advance has catalysed a large number of new experimental and theoretical investigations of Criegee intermediate chemistry. In this article we review the physical chemistry of Criegee intermediates, focusing on their molecular structure, spectroscopy, unimolecular and bimolecular reactions. These recent results have overturned conclusions from some previous studies, while confirming others, and have clarified areas of investigation that will be critical targets for future studies. In addition to expanding our fundamental understanding of Criegee intermediates, the rapidly expanding knowledge base will support increasingly predictive models of their impacts on society.
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Cites
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Direct Kinetic Measurements of Criegee Intermediate (CH 2 OO) Formed by Reaction of CH 2 I with O 2
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Self-citationKinetics of elementary reactions in low-temperature autoignition chemistry
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Self-citationA new atmospherically relevant oxidant of sulphur dioxide
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Self-citationChemistry – A European Journal
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Cited by
Jiang, B., Li, J., & Guo, H. (2016) · International Reviews in Physical Chemistry · doi:10.1080/0144235x.2016.1200347 · Cited by 401
Unimolecular decay strongly limits the atmospheric impact of Criegee intermediates
Vereecken, L., Novelli, A., & Taraborrelli, D. (2017) · Physical Chemistry Chemical Physics · doi:10.1039/c7cp05541b · Cited by 257
Taatjes, C. A., Khan, M. A. H., Eskola, A. J., Percival, C. J., Osborn, D. L., Wallington, T. J., & Shallcross, D. E. (2019) · Environmental Science & Technology · doi:10.1021/acs.est.8b05073 · Cited by 38
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Metadata
- Authors
- Osborn, D. L., & Taatjes, C. A.
- Venue
- International Reviews in Physical Chemistry
- Publisher
- Informa UK Limited
- Published
- 2015-07-03
- Volume
- 34
- Issue
- 3
- Pages
- 309-360
- ISSN
- 0144-235X (ISSN-L)
- 1366-591X
- OpenAlex
- W1671161451
- Cited by
- 265
- References
- 31
- FWCI
- 24.74
- Type
- journal article
- Language
- en
- Open access
- green
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