Cited by 200Catalysis for Biomass ConversionChemical Synthesis and ReactionsCatalysts for Methane Reforming

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Recent Advances in Catalytic Conversion of Glycerol

Zhou, Chun Hui, Zhao, Heng, Tong, Dong Shen, Wu, Lin Mei, Yu, Wei Hua·2013·Catalysis Reviews

DOI 10.1080/01614940.2013.816610

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Abstract

The article underlines and discusses the state-of-the-art accomplishments in the catalytic conversion of glycerol (1,2,3-propanetriol) to fuels and value-added chemicals in the past five years (2008–2012). The reactions include steam reforming, aqueous-phase reforming, hydrogenolysis, oxidation, dehydration, esterification, etherification, carboxylation, acetalization, and chlorination. Typical products are hydrogen, propanediols, dihydroxyacetone, glyceric acid, acrolein, glyceride, polyglycerol, glycerol carbonate, acetals, ketals, and epichlorohydrine. Recent studies on the catalysts, reaction conditions, and possible pathways are primarily discussed. They indicate that major breakthroughs are achieved by the use of multifunctional catalysts, process intensification and integrated reactions. Literature survey suggests that future work on the catalytic conversion of glycerol for commercial goals particularly requires new catalysts, innovative reactor engineering, and close multidisciplinary partnership.

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Design of new solid catalysts for the selective conversion of glycerol
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Electrochemical reforming of an acidic aqueous glycerol solution on Pt electrodes
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Liquid Phase Oxidation of Glycerol Using a Single Phase (Au–Pd) Alloy Supported on Activated Carbon: Effect of Reaction Conditions
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Glycerol Hydrogenolysis over Co Catalysts Derived from a Layered Double Hydroxide Precursor
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Esterification of glycerol by lauric acid over aluminium and zirconium containing mesoporous molecular sieves in supercritical carbon dioxide medium
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Selective Oxidation of Glycerol Catalyzed by Rh/Activated Carbon: Importance of Support Surface Chemistry
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Oxidation of Reactive Alcohols with Hydrogen Peroxide Catalyzed by Manganese Complexes
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Low‐pressure packed‐bed gas phase conversion of glycerol to acetol
Chiu, C., Tekeei, A., Sutterlin, W. R., et al. (2008) · AIChE Journal · doi:10.1002/aic.11567 · Cited by 54
Etherification of Glycerol by tert-Butyl Alcohol: Kinetic Model
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Entrainer-Based Reactive Distillation for Esterification of Glycerol with Acetic Acid
Hasabnis, A., & Mahajani, S. M. (2010) · Industrial & Engineering Chemistry Research · doi:10.1021/ie100937p · Cited by 53
Influence of Reactor Configuration on the Selective Oxidation of Glycerol over Au/TiO2
Zope, B. N., & Davis, R. J. (2009) · Topics in Catalysis · doi:10.1007/s11244-008-9163-3 · Cited by 53
Isolation of Dunaliella spp. from a hypersaline lake and their ability to accumulate glycerol
Kaçka, A., & Dönmez, G. (2008) · Bioresource Technology · doi:10.1016/j.biortech.2008.02.042 · Cited by 52
Direct preparation of dichloropropanol (DCP) from glycerol using heteropolyacid (HPA) catalysts: A catalyst screen study
Lee, S. H., Park, D. R., Kim, H., et al. (2008) · Catalysis Communications · doi:10.1016/j.catcom.2008.03.020 · Cited by 50
Straightforward selective synthesis of linear 1-O-alkyl glycerol and di-glycerol monoethers
Shi, Y., Dayoub, W., Favre‐Réguillon, A., et al. (2009) · Tetrahedron Letters · doi:10.1016/j.tetlet.2009.09.134 · Cited by 50
Polyisobutylene Modified Bisphenol A Diglycidyl Ether Based Epoxy Resins Possessing Improved Mechanical Properties
Tripathy, R., Ojha, U., & Faust, R. (2011) · Macromolecules · doi:10.1021/ma201081y · Cited by 49
Catalytic oxidation of crude glycerol using catalysts based on Au supported on carbonaceous materials
Gil, S., Marchena, M., Fernandez-Marchante, C. M., Sánchez-Silva, L., Romero, A., & Valverde, J. L. (2012) · Applied Catalysis A General · doi:10.1016/j.apcata.2012.10.024 · Cited by 47
Preparation of a Novel Carbon Based Solid Acid Catalyst for Biodiesel Production via a Sustainable Route
Song, X., Fu, X., Zhang, C., et al. (2012) · Catalysis Letters · doi:10.1007/s10562-012-0840-2 · Cited by 47
Role of promoters in copper chromite catalysts for hydrogenolysis of glycerol
Mane, R. B., Ghalwadkar, A., Hengne, A. M., et al. (2010) · Catalysis Today · doi:10.1016/j.cattod.2010.10.032 · Cited by 47
Reducing Byproduct Formation during Conversion of Glycerol to Propylene Glycol
Chiu, C., Tekeei, A., Ronco, J. M., et al. (2008) · Industrial & Engineering Chemistry Research · doi:10.1021/ie800300a · Cited by 46
Novel Esterification of Glycerol Catalysed by Tin Chloride (II): A Recyclable and Less Corrosive Process for Production of Bio-Additives
Gonçalves, C. E., Laier, L. O., & da Silva, M. J. (2011) · Catalysis Letters · doi:10.1007/s10562-011-0570-x · Cited by 46
Studies on the conversion of glycerol to 1,2-propanediol over Ru-based catalyst under mild conditions
Lee, S. H., & Moon, D. J. (2011) · Catalysis Today · doi:10.1016/j.cattod.2011.03.071 · Cited by 46
Anaerobic glycerol production by Saccharomyces cerevisiae strains under hyperosmotic stress
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Characterization of alumina- and niobia-supported gold catalysts used for oxidation of glycerol
Musialska, K., Finocchio, E., Sobczak, I., Busca, G., Wojcieszak, R., Gaigneaux, É. M., & Ziółek, M. (2010) · Applied Catalysis A General · doi:10.1016/j.apcata.2010.06.006 · Cited by 45
Hydrogen production from water gas shift reaction in a high gravity (Higee) environment using a rotating packed bed
Chen, W., & Syu, Y.-J. (2010) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2010.07.126 · Cited by 44
Batch Study of Glycerol Decomposition in One-Stage Supercritical Production of Biodiesel
Aimaretti, N. R., Manuale, D. L., Mazzieri, V. M., et al. (2009) · Energy & Fuels · doi:10.1021/ef8008585 · Cited by 43
Use of delaminated hectorites as supports of copper catalysts for the hydrogenolysis of glycerol to 1,2-propanediol
Sánchez, T., Salagre, P., Cesteros, Y., et al. (2011) · Chemical Engineering Journal · doi:10.1016/j.cej.2011.11.011 · Cited by 43
Catalytic Thermochemical Conversion of Glycerol to Simple and Polyhydric Alcohols Using Raney Nickel Catalyst
Maglinao, R. L., & He, B. (2011) · Industrial & Engineering Chemistry Research · doi:10.1021/ie102573m · Cited by 42
Glycerol hydrogenolysis to 1, 2 propanediol over Ru/C catalyst
Bolado, S., Treviño, R. E., Cubero, M. T. G., et al. (2010) · Catalysis Communications · doi:10.1016/j.catcom.2010.08.016 · Cited by 41
Palladium‐Catalysed Telomerisation of Isoprene with Glycerol and Polyethylene Glycol: A Facile Route to New Terpene Derivatives
Gordillo, Á., Pachón, L. D., de Jesús, E., et al. (2009) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.200800675 · Cited by 41
Synthesis of glycerol triacetate using functionalized ionic liquid as catalyst
Lu, L. P., Yu, S., Xie, C., et al. (2009) · Journal of Chemical Technology & Biotechnology · doi:10.1002/jctb.2223 · Cited by 40
Hydrogenolysis of Aqueous Glycerol over Raney Nickel Catalyst: Comparison of Pure and Biodiesel By-Product
Hoşgün, H. L., Yıldız, M., & Gerçel, H. F. (2012) · Industrial & Engineering Chemistry Research · doi:10.1021/ie201781q · Cited by 40
Plasma reforming of glycerol for synthesis gas production
Zhu, X., Hoang, T. Q., Lobban, L. L., et al. (2009) · Chemical Communications · doi:10.1039/b823410h · Cited by 39
The Promotion Effect of Cr on Copper Catalyst in Hydrogenolysis of Glycerol to Propylene Glycol
Kim, N. D., Oh, S., Joo, J. B., et al. (2010) · Topics in Catalysis · doi:10.1007/s11244-010-9480-1 · Cited by 39
Selective Conversion of Glycerol to Propylene Glycol Over Fixed Bed Raney® Cu Catalysts
Schmidt, S. R., Tanielyan, S. K., Marin, N., Alvez, G., & Augustine, R. L. (2010) · Topics in Catalysis · doi:10.1007/s11244-010-9565-x · Cited by 38
Activity of nanocasted oxides for gas-phase dehydration of glycerol
Vasconcelos, S. J. S., Lima, C. L., Filho, J. M., et al. (2011) · Chemical Engineering Journal · doi:10.1016/j.cej.2011.01.053 · Cited by 38
On Achieving Experimental Accuracy from Molecular Dynamics Simulations of Flexible Molecules: Aqueous Glycerol
Yongye, A. B., Foley, B. L., & Woods, R. J. (2008) · The Journal of Physical Chemistry A · doi:10.1021/jp710544s · Cited by 38
Glycerol hydrogenolysis to propylene glycol
Marinoiu, A., Ioniţă, G., Gáspár, C.-L., et al. (2009) · Reaction Kinetics and Catalysis Letters · doi:10.1007/s11144-009-0032-2 · Cited by 38
A Solvent-Free Method for Making Dioxolane and Dioxane from the Biorenewables Glycerol and Furfural Catalyzed by Oxorhenium(V) Oxazoline
Wegenhart, B. L., & Abu‐Omar, M. M. (2010) · Inorganic Chemistry · doi:10.1021/ic1004352 · Cited by 37
Catalytic Synthesis of Glycerol Monoacetate Using a Continuous Expanded Bed Column Reactor Packed with Cation-Exchange Resin
Fukumura, T., Toda, T., Seki, Y., et al. (2009) · Industrial & Engineering Chemistry Research · doi:10.1021/ie800625g · Cited by 36
The antioxidant and anticorrosive properties of crude glycerol fraction from biodiesel production
Jerzykiewicz, M., Ćwieląg‐Piasecka, I., & JERZYKIEWICZ, W. (2009) · Journal of Chemical Technology & Biotechnology · doi:10.1002/jctb.2157 · Cited by 36
Conversion of Glycerol to Ethylene Glycol over Pt-modified Ni Catalyst
Ueda, N., Nakagawa, Y., & Tomishige, K. (2010) · Chemistry Letters · doi:10.1246/cl.2010.506 · Cited by 35
Effects of Sorption Enhancement and Isobutene Formation on Etherification of Glycerol with tert-Butyl Alcohol in a Flow Reactor
Özbay, N., Oktar, N., Doğu, G., et al. (2011) · Industrial & Engineering Chemistry Research · doi:10.1021/ie201720q · Cited by 34
New synthesis of glycerol carbonate from glycerol using sulfur‐assisted carbonylation with carbon monoxide
Mizuno, T., Nakai, T., & Mihara, M. (2010) · Heteroatom Chemistry · doi:10.1002/hc.20583 · Cited by 33
Hydrogenolysis of glycerol to 1,2‐propanediol catalyzed by Cu‐H4SiW12O40/Al2O3 in liquid phase
Hao, S., Peng, W., Zhao, N., Xiao, F., Wei, W., & Sun, Y. (2010) · Journal of Chemical Technology & Biotechnology · doi:10.1002/jctb.2456 · Cited by 32
Tuning of diglycerol yield and isomer distribution in oligomerization of glycerol supported by DFT-calculations
Martin, A., Chęciński, M. P., & Richter, M. (2011) · Catalysis Communications · doi:10.1016/j.catcom.2011.10.013 · Cited by 32
Gold nanoclusters as colloidal catalysts for oxidation of long chain aliphatic 1,2-diols in alcohol solvents
Mertens, P. G. N., Vankelecom, I. F. J., Jacobs, P. A., et al. (2005) · Gold bulletin · doi:10.1007/bf03215255 · Cited by 31
Effect of N2O-mediated calcination on nickel species and the catalytic activity of nickel catalysts supported on γ-Al2O3 in the steam reforming of glycerol
Choi, Y., Kim, N. D., Baek, J., et al. (2011) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2010.12.081 · Cited by 30
Synthesis of acrolein by gas‐phase dehydration of glycerol over silica supported Bronsted acidic ionic liquid catalysts
Munshi, M. K., Lomate, S. T., Deshpande, R. M., et al. (2010) · Journal of Chemical Technology & Biotechnology · doi:10.1002/jctb.2434 · Cited by 30
Catalyst-free synthesis of octahydroacridines using glycerol as recyclable solvent
Nascimento, J. E. R., Barcellos, A. M., Sachini, M., et al. (2011) · Tetrahedron Letters · doi:10.1016/j.tetlet.2011.03.045 · Cited by 29
Continuous reactive extraction for selective telomerisation of butadiene with glycerol in a miniplant
Behr, A., Leschinski, J., Prinz, A., et al. (2009) · Chemical Engineering and Processing - Process Intensification · doi:10.1016/j.cep.2009.03.005 · Cited by 28
Recovery of Glycerol from Spent Soap LyeBy ‐ Product of Soap Manufacture
Israel, A. U., Obot, I. B. B., & Asuquo, J. E. (2007) · Journal of Chemistry · doi:10.1155/2008/302609 · Cited by 28
TPD‐TG‐MS Investigations of the Catalytic Conversion of Glycerol over MOx‐Al2O3‐PO4 Catalysts
Suprun, W. Y., Lutecki, M., & Papp, H. (2010) · Chemical Engineering & Technology · doi:10.1002/ceat.201000316 · Cited by 27
Telomerisation of 1,3-butadiene with glycerol under aqueous biphasic conditions: Influence of the reaction conditions on the products distribution
Bigot, S., Lai, J., Suisse, I., et al. (2010) · Applied Catalysis A General · doi:10.1016/j.apcata.2010.04.039 · Cited by 26
Direct Preparation Kinetics of 1,3-Dichloro-2-propanol from Glycerol Using Acetic Acid Catalyst
Luo, Z., You, X.-Z., & Li, H.-R. (2008) · Industrial & Engineering Chemistry Research · doi:10.1021/ie8011177 · Cited by 26
A new efficient approach to 3-methylindole: Vapor-phase synthesis from aniline and glycerol over Cu-based catalyst
Sun, W., Liu, D., Zhu, H., et al. (2010) · Catalysis Communications · doi:10.1016/j.catcom.2010.08.011 · Cited by 25
Vapor-phase Beckmann rearrangement of cyclohexanone oxime over phosphorus modified Si-MCM-41
Zhang, D., Wang, R., Yang, X., et al. (2010) · Reaction Kinetics Mechanisms and Catalysis · doi:10.1007/s11144-010-0226-7 · Cited by 25
Long-Time Behavior of the Catalytic Partial Oxidation of Glycerol in an Autothermal Reactor
Rennard, D. C., Kruger, J. S., Michael, B. C., et al. (2010) · Industrial & Engineering Chemistry Research · doi:10.1021/ie100405h · Cited by 25
Hydrogen Production by Glycerol Steam Reforming with Ru‐based Catalysts: A Study on Sn Doping
Gallo, A., Pirovano, C., Marelli, M., et al. (2010) · Chemical Vapor Deposition · doi:10.1002/cvde.201006864 · Cited by 24
Metabolically engineered Escherichia coli as a tool for the production of bioenergy and biochemicals from glycerol
Ganesh, I., Ravikumar, S., & Hong, S. H. (2012) · Biotechnology and Bioprocess Engineering · doi:10.1007/s12257-011-0446-3 · Cited by 24
Effect of tetramethyl ammonium hydroxide on the activity of LiOH-intercalated montmorillonite catalyst in the transesterification of methyl laurate with glycerol
Abdullah, A. Z., Wibowo, T. Y., & Zakaria, R. (2011) · Chemical Engineering Journal · doi:10.1016/j.cej.2010.12.078 · Cited by 24
Influence of Parameters on Glycerol Hydrogenolysis over a Cu/Al2O3 Catalyst
Wołosiak‐Hnat, A., Milchert, E., & Grzmil, B. U. (2013) · Chemical Engineering & Technology · doi:10.1002/ceat.201200549 · Cited by 24
Catalytic performance of polymer-supported ionic liquids in the synthesis of glycerol carbonate from glycerol and urea
Kim, D.-W., Park, M.-S., Selvaraj, M., et al. (2011) · Research on Chemical Intermediates · doi:10.1007/s11164-011-0398-4 · Cited by 23
Preparation and Characterization of 4‐Methoxy Cinnamoyl Glycerol
Holser, R. A., Mitchell, T. R., Harry‐O'kuru, R. E., et al. (2008) · Journal of the American Oil Chemists Society · doi:10.1007/s11746-008-1197-y · Cited by 23
The oxidative esterification of glycerol to methyl glycerate in methanol using gold on oxidic supports: an insight in product selectivity
Purushothaman, R. K. P., van Haveren, J., van Es, D. S., et al. (2012) · Green Chemistry · doi:10.1039/c2gc35226e · Cited by 22
Optimal Separation of Glycerol and Methyl Oleate via Liquid−Liquid Extraction
Tizvar, R., McLean, D. D., Kates, M., et al. (2009) · Journal of Chemical & Engineering Data · doi:10.1021/je8008655 · Cited by 22
Gold– and gold–palladium/poly(1-vinylpyrrolidin-2-one) nanoclusters as quasi-homogeneous catalyst for aerobic oxidation of glycerol
Salprima Yudha, S., Dhital, R. N., & Sakurai, H. (2011) · Tetrahedron Letters · doi:10.1016/j.tetlet.2011.03.027 · Cited by 22
Microwave spectrum of glycerol: Observation of a tunneling chiral isomer
Ilyushin, V. V., Motiyenko, R. A., Lovas, F. J., et al. (2008) · Journal of Molecular Spectroscopy · doi:10.1016/j.jms.2008.02.005 · Cited by 22
Catalytic Transformation of Glycerol
Sels, B. F., D’Hondt, E., & Jacobs, P. A. (2007) · doi:10.1002/9783527621118.ch11 · Cited by 21
Synthesis of superacidic mesoporous alumina and its application in the dehydration of glycerol
Yang, L., Joo, J. B., Kim, Y. J., et al. (2008) · Korean Journal of Chemical Engineering · doi:10.1007/s11814-008-0164-5 · Cited by 21
Influence of the synthesis process on the properties of flow and oxidative stability of biodiesel from Jatropha curcas biodiesel
Freire, L. M. D. S., Santos, I. M. G., Filho, J. R. D. C., et al. (2011) · Fuel · doi:10.1016/j.fuel.2011.10.054 · Cited by 21
Integrated aqueous-phase glycerol reforming to dimethyl ether synthesis—A novel allothermal dual bed membrane reactor concept
Iliuta, I., Iliuta, M. C., Fongarland, P., et al. (2012) · Chemical Engineering Journal · doi:10.1016/j.cej.2012.02.001 · Cited by 21
Theoretical study of the dynamics and thermal mechanisms of the reaction: Dehydration of glycerol to glycidol
Sun, W., Liu, J., Chu, X., et al. (2009) · Journal of Molecular Structure THEOCHEM · doi:10.1016/j.theochem.2009.11.030 · Cited by 21
Synthesis and characterization of hyperbranched polyesters from glycerol‐based AB2 monomer
Parzuchowski, P. G., Grabowska, M., Jaroch, M., & Kusznerczuk, M. (2009) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.23452 · Cited by 21
Solvent-free direct preparation of dichloropropanol from glycerol and hydrochloric acid gas in the presence of H3PMo12−W O40 catalyst and/or water absorbent
Lee, S. H., Song, S. H., Park, D. R., Jung, J. C., Song, J. H., Woo, S. Y., Song, W. S., Kwon, M. S., & Song, I. K. (2008) · Catalysis Communications · doi:10.1016/j.catcom.2008.08.011 · Cited by 20
Hydrogenolysis of glycerol to 1,2-propanediol on the high dispersed SBA-15 supported copper catalyst prepared by the ion-exchange method
Zheng, J., Zhu, W., Ma, C., et al. (2010) · Reaction Kinetics Mechanisms and Catalysis · doi:10.1007/s11144-009-0127-9 · Cited by 20
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Organo-montmorillonites as catalysts for selective synthesis of glycerol monolaurate
Wibowo, T. Y., Abdullah, A. Z., & Zakaria, R. (2010) · Applied Clay Science · doi:10.1016/j.clay.2010.07.009 · Cited by 18
Direct preparation of dichloropropanol from glycerol and hydrochloric acid gas in a solvent-free batch reactor: Effect of experimental conditions
Song, S. H., Lee, S. H., Park, D. R., et al. (2009) · Korean Journal of Chemical Engineering · doi:10.1007/s11814-009-0064-3 · Cited by 15
Simple one-pot synthesis of a mesoporous superacidic catalyst for the dehydration of glycerol to acrolein
Yang, L., Joo, J. B., Kim, N. D., et al. (2010) · Korean Journal of Chemical Engineering · doi:10.1007/s11814-010-0256-x · Cited by 15
Influence of nitrogen on the catalytic behaviour of Pt/γ-Al2O3 catalyst in glycerol reforming process
Luo, N., Wang, J. A., Xiao, T., et al. (2010) · Catalysis Today · doi:10.1016/j.cattod.2010.04.013 · Cited by 15
Pd-catalyzed Suzuki cross-coupling reactions of glycerol arylboronic esters
Nichele, T. Z., Favero, C., & Monteiro, A. L. (2008) · Catalysis Communications · doi:10.1016/j.catcom.2008.11.021 · Cited by 14
Novel branched poly(l-lactide) with poly(glycerol-co-sebacate) core
Cheng, S., Li-jing, Y., & Gong, F. (2010) · Polymer Bulletin · doi:10.1007/s00289-009-0237-6 · Cited by 13
Process conditions for preparing methanol from cornstalk gas
Zhu, L., Lei, D. U., Li, X., et al. (2007) · Journal of Environmental Sciences · doi:10.1016/s1001-0742(07)60104-1 · Cited by 12
Glycerol-Intercalated Mg-Al Hydrotalcite as a Potential Solid Base Catalyst for Transesterification
Xi, Y., & Davis, R. J. (2010) · Clays and Clay Minerals · doi:10.1346/ccmn.2010.0580403 · Cited by 12
Direct preparation of dichloropropanol from glycerol and hydrochloric acid gas using heteropolyacid (HPA) catalyst by heterogeneous gas phase reaction
Song, S. H., Park, D. R., Woo, S. Y., et al. (2010) · Journal of Industrial and Engineering Chemistry · doi:10.1016/j.jiec.2010.05.012 · Cited by 12
Aeration alleviates ethanol inhibition and glycerol production during fed-batch ethanol fermentation
Seo, H.-B., Yeon, J.-H., Jeong, M. H., Kang, D. H., Lee, H.-Y., & Jung, K. (2009) · Biotechnology and Bioprocess Engineering · doi:10.1007/s12257-009-0066-3 · Cited by 11
Initial Scale-Up and Process Improvements for the Preparation of a Lead Antibacterial Macrolone Compound
Štimac, V., Škugor, M. M., Jakopović, I. P., et al. (2010) · Organic Process Research & Development · doi:10.1021/op100199t · Cited by 10
Thermal, kinetic, and mechanical properties of glycerol‐plasticized wheat gluten
Pan, Y., Wang, X., & Yuan, Q. (2011) · Journal of Applied Polymer Science · doi:10.1002/app.33512 · Cited by 8
Regeneration of H3PW12O40 catalyst in the direct preparation of dichloropropanol (DCP) from glycerol and hydrochloric acid gas
Song, S. H., Lee, S. H., Park, D. R., et al. (2009) · Korean Journal of Chemical Engineering · doi:10.1007/s11814-009-0245-0 · Cited by 8
Selective Conversion of Glycerol into Functional Monomers via Catalytic Processes
Jérôme, F., & Barrault, J. (2011) · doi:10.1002/9783527636167.ch4 · Cited by 6
Novel Route for Recovery of Glycerol from Aqueous Solutions by Reversible Reactions
Ch, V. L., Ravuru, U., Kotra, V., et al. (2009) · International Journal of Chemical Reactor Engineering · doi:10.2202/1542-6580.2054 · Cited by 6
Glycerol extracting dealcoholization for the biodiesel separation process
Ye, J., Sha, Y., Zhang, Y., et al. (2011) · Bioresource Technology · doi:10.1016/j.biortech.2011.01.026 · Cited by 6
Evidence for sub-3 nanometer neutralized particle detection using glycerol as a condensing fluid
Magnusson, L.-E., Anisimov, M. P., & Koropchak, J. A. (2010) · Journal of Aerosol Science · doi:10.1016/j.jaerosci.2010.04.002 · Cited by 5
Granulation of sludge under different loads of a glycerol fraction from biodiesel production
Cydzik‐Kwiatkowska, A., Wojnowska‐Baryła, I., & Selewska, K. (2010) · European Journal of Lipid Science and Technology · doi:10.1002/ejlt.200900260 · Cited by 5
Process conditions for preparing methanol from cornstalk gas
Zhu, Ling-feng, Du, et al. (2007) · Acta Scientiarum Naturalium Universitatis Sunyatseni · Cited by 5
Hydrogenolysis of glycerol with FeCo macrocyclic complex bonded to Raney Nickel support under mild reaction conditions
Anand, K. A., Anisia, K. S., Ágarwal, A. K., et al. (2010) · The Canadian Journal of Chemical Engineering · doi:10.1002/cjce.20273 · Cited by 4

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Catalysis as an Enabling Science for Sustainable Polymers
Zhang, X., Fevre, M., Jones, G. O., & Waymouth, R. M. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00329 · Cited by 936

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Authors: Zhou, C. H., Zhao, H., Tong, D. S., Wu, L. M., & Yu, W. H.
Affiliations: Zhejiang University of Technology (CN)
Corresponding author: Zhou, Chun Hui
ORCID: Zhou, Chun Hui
Zhao, Heng
Yu, Wei Hua
Venue: Catalysis Reviews
Publisher: Informa UK Limited
Published: 2013-10-02
Volume: 55
Issue: 4
Pages: 369-453
ISSN: 0161-4940 (ISSN-L)
1520-5703
DOI: 10.1080/01614940.2013.816610
OpenAlex: W2015144962
Cited by: 200
References: 397
Citations by year: 2026: 7 · 2025: 9 · 2024: 10 · 2023: 8 · 2022: 14 · 2021: 10 · 2020: 17 · 2019: 16 · 2018: 12 · 2017: 31 · 2016: 22 · 2015: 20 · 2014: 24
FWCI: 12.14
Type: journal article
Language: en
Open access: closed
Locations: Catalysis Reviews (publishedVersion)
Topics: Physical Sciences › Chemical Engineering › Catalysis › Catalysis for Biomass Conversion
Physical Sciences › Chemistry › Organic Chemistry › Chemical Synthesis and Reactions
Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
Keywords: glycerol, catalytic conversion, steam reforming, aqueous phase reforming, hydrogenolysis, glycerol oxidation, dehydration, esterification, etherification, carboxylation, acetalization, chlorination, multifunctional catalysts, process intensification, hydrogen production, propanediol, dihydroxyacetone, glyceric acid, acrolein, polyglycerol, glycerol carbonate, epichlorohydrin, acetals, ketals

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