Cited by 200Catalysis for Biomass ConversionChemical Synthesis and ReactionsCatalysts for Methane Reforming

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Recent Advances in Catalytic Conversion of Glycerol

Zhou, Chun Hui, Zhao, Heng, Tong, Dong Shen, Wu, Lin Mei, Yu, Wei Hua·2013·Catalysis Reviews

DOI 10.1080/01614940.2013.816610

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Abstract

The article underlines and discusses the state-of-the-art accomplishments in the catalytic conversion of glycerol (1,2,3-propanetriol) to fuels and value-added chemicals in the past five years (2008–2012). The reactions include steam reforming, aqueous-phase reforming, hydrogenolysis, oxidation, dehydration, esterification, etherification, carboxylation, acetalization, and chlorination. Typical products are hydrogen, propanediols, dihydroxyacetone, glyceric acid, acrolein, glyceride, polyglycerol, glycerol carbonate, acetals, ketals, and epichlorohydrine. Recent studies on the catalysts, reaction conditions, and possible pathways are primarily discussed. They indicate that major breakthroughs are achieved by the use of multifunctional catalysts, process intensification and integrated reactions. Literature survey suggests that future work on the catalytic conversion of glycerol for commercial goals particularly requires new catalysts, innovative reactor engineering, and close multidisciplinary partnership.

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A LCA (life cycle assessment) of the methanol production from sugarcane bagasse
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Glycerin as a Renewable Feedstock for Epichlorohydrin Production. The GTE Process
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A glycerol-free process to produce biodiesel by supercritical methyl acetate technology: An optimization study via Response Surface Methodology
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Sorted by citations

Catalysis as an Enabling Science for Sustainable Polymers
Zhang, X., Fevre, M., Jones, G. O., & Waymouth, R. M. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00329 · Cited by 936

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Authors: Zhou, C. H., Zhao, H., Tong, D. S., Wu, L. M., & Yu, W. H.
Affiliations: Zhejiang University of Technology (CN)
Corresponding author: Zhou, Chun Hui
ORCID: Zhou, Chun Hui
Zhao, Heng
Yu, Wei Hua
Venue: Catalysis Reviews
Publisher: Informa UK Limited
Published: 2013-10-02
Volume: 55
Issue: 4
Pages: 369-453
ISSN: 0161-4940 (ISSN-L)
1520-5703
DOI: 10.1080/01614940.2013.816610
OpenAlex: W2015144962
Cited by: 200
References: 397
Citations by year: 2026: 7 · 2025: 9 · 2024: 10 · 2023: 8 · 2022: 14 · 2021: 10 · 2020: 17 · 2019: 16 · 2018: 12 · 2017: 31 · 2016: 22 · 2015: 20 · 2014: 24
FWCI: 12.14
Type: journal article
Language: en
Open access: closed
Locations: Catalysis Reviews (publishedVersion)
Topics: Physical Sciences › Chemical Engineering › Catalysis › Catalysis for Biomass Conversion
Physical Sciences › Chemistry › Organic Chemistry › Chemical Synthesis and Reactions
Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
Keywords: glycerol, catalytic conversion, steam reforming, aqueous phase reforming, hydrogenolysis, glycerol oxidation, dehydration, esterification, etherification, carboxylation, acetalization, chlorination, multifunctional catalysts, process intensification, hydrogen production, propanediol, dihydroxyacetone, glyceric acid, acrolein, polyglycerol, glycerol carbonate, epichlorohydrin, acetals, ketals

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