Chemical Composition of Spent Liquors from Acidic Magnesium–Based Sulphite Pulping of Eucalyptus globulus
Abstract
The major components of industrial thin (SSL) and thick (THSL) liquors from acidic magnesium–based sulphite pulping of Eucalyptus globulus wood have been characterized. The analysis of sugars in SSL revealed the predominance of xylose, which was present in the form of sugar monomer (ca. 70%) and as xylo-oligosaccharides (ca. 30%). Lignosulphonates (LS) were the most abundant organic fraction of spent liquor (ca. 50% of liquor dry matter) consisting of sulphonated oligomers (SO3H ≈ 20% w/w) of low molecular weight (Mw ≈ 1000–1300 Da) and constituted mainly by syringyl units (syringyl:guaiacyl ratio = 81:19). The major phenolic extractives of THSL were pyrogallol (93 g/ton) and gallic acid (1020 g/ton), and the most abundant fatty acid and sterol were tetracosanoic acid (6 g/ton) and β -sitosterol (45 g/ton), respectively. The structural changes of macromolecular components during the liquor evaporation were discussed.
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Native lignin prevents access of polysaccharide hydrolases to their substrates.
“Native lignin not only prevents access of polysaccharide hydrolases to their substrates, but modified lignin adhering to the pulp after pretreatment also causes unproductive binding of hydrolases.25”
From Deconstruction of lignocellulosic biomass with ionic liquids (2013) · cites this paper as [25]
Modified lignin adhering to pulp after pretreatment causes unproductive binding of hydrolases.
“Native lignin not only prevents access of polysaccharide hydrolases to their substrates, but modified lignin adhering to the pulp after pretreatment also causes unproductive binding of hydrolases.25”
From Deconstruction of lignocellulosic biomass with ionic liquids (2013) · cites this paper as [25]
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- Authors
- Marques, A. P., Evtuguin, D. V., Magina, S., Amado, F. M. L., & Prates, A.
- Affiliations
- University of Aveiro (PT)
- Venue
- Journal of Wood Chemistry and Technology
- Publisher
- Informa UK Limited
- Published
- 2009-11-30
- Volume
- 29
- Issue
- 4
- Pages
- 322-336
- ISSN
- 0277-3813 (ISSN-L)
- 1532-2319
- OpenAlex
- W2152544651
- Cited by
- 75
- References
- 19
- Citations by year
- 2025: 2 · 2024: 5 · 2023: 1 · 2022: 8 · 2021: 4 · 2020: 4 · 2019: 3 · 2018: 11 · 2017: 5 · 2016: 9 · 2015: 4 · 2014: 5 · 2013: 1 · 2012: 7
- FWCI
- 2.60
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Wood Chemistry and Technology (publishedVersion)
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Lignin and Wood Chemistry
- Physical Sciences › Engineering › Building and Construction › Wood Treatment and Properties
- Physical Sciences › Engineering › Biomedical Engineering › Biofuel production and bioconversion
- Keywords
- spent liquor, Eucalyptus globulus, lignosulfonate, xylooligosaccharides, xylose, phenolic extractives, pyrogallol, gallic acid, fatty acids, sterols, tetracosanoic acid, β-sitosterol, chemical composition
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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