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THE LITHIUM CHLORIDE/DIMETHYLACETAMIDE SOLVENT FOR CELLULOSE: A LITERATURE REVIEW
Abstract
Cellulose or poly(1·4)-β-D-D-glucose is the most abundant, renewable organic raw material [1]. The molocular structure (Fig. 1) consists of cellobiose repeating units which allow chain-packing by intermolecular [2] and intramolecular [3] hydrogen-bonding. Such strong interactions are responsible for excellent inherent mechanical properties, yet at the same time, interfere with efforts to process or modify the material. Only in a few instances have cellulose derivatives been exploited commercially and certainly not to the extent predicted from raw material availability and cost. Controllable, uniform derivatization has been hampered by the lack of suitable, nondegrading solvents or by a limited range of synthetic reactions within these solvents.
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Cited by
Cellulose: Fascinating Biopolymer and Sustainable Raw Material
Klemm, D., Heublein, B., Fink, H., & Bohn, A. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200460587 · Cited by 7,551
A review of chitin and chitosan applications
Ravi Kumar, M. N. V. (2000) · Reactive and Functional Polymers · doi:10.1016/s1381-5148(00)00038-9 · Cited by 6,009
Cellulose nanocrystals: chemistry, self-assembly, and applications
Habibi, Y., Lucia, L. A., & Rojas, O. J. (2010) · Chemical Reviews · doi:10.1021/cr900339w · Cited by 5,980
Chitin and chitosan polymers: Chemistry, solubility and fiber formation
Pillai, C. K. S., Paul, W., & Sharma, C. P. (2009) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2009.04.001 · Cited by 2,745
Rapid Dissolution of Cellulose in LiOH/Urea and NaOH/Urea Aqueous Solutions
Cai, J., & Zhang, L. (2005) · Macromolecular Bioscience · doi:10.1002/mabi.200400222 · Cited by 1,047
Metadata
- Authors
- Dawsey, T. R., & McCormick, C. L.
- Venue
- Journal of Macromolecular Science, Part C
- Publisher
- Informa UK Limited
- Published
- 1990-08
- Volume
- 30
- Issue
- 3-4
- Pages
- 405-440
- ISSN
- 0736-6574 (ISSN-L)
- 1532-1797
- 1520-5746
- OpenAlex
- W1999625725
- Cited by
- 333
- References
- 0
- FWCI
- 2.96
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: THE LITHIUM CHLORIDE/DIMETHYLACETAMIDE SOLVENT FOR CELLULOSE: A LITERATURE REVIEW. https://app.cochat.ai/papers/10.1080/07366579008050914
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- Dawsey, T. R., & McCormick, C. L. (1990). THE LITHIUM CHLORIDE/DIMETHYLACETAMIDE SOLVENT FOR CELLULOSE: A LITERATURE REVIEW. Journal of Macromolecular Science, Part C. https://doi.org/10.1080/07366579008050914
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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