The DOI matches its Crossref record; 19 of the 19 references it cites were found in a registry or an index.
The Development of Functional Group Tolerant Romp Catalysts
Abstract
Since the discovery that transition metals salts mixed with organoaluminum reagents catalyze the polymerization of ethylene to crystalline polyethylene, organo-metallic complexes and reagents have played a major role in the polymer industry [1]. Over the past 20 years a tremendous amount has been learned about the structures and mechanisms of reactions of complexes related to those proposed to be active in these systems [2]. In the related area of olefin metathesis and ring-opening metathesis polymerization (ROMP), metal carbenes and metallacycles were proposed intermediates, and over the past few years a number of complexes with these structures that will catalyze the olefin metathesis reaction have been prepared and studied [3]. In contrast to the ill-defined classical catalysts based on Ziegler-type catalysts, these are living polymerization systems. This was first observed using Tebbe-type reagents [4].
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“whereas the titanium complexes are sensitive to almost all impurities [144].”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [144]
In the citing paper
“thus, ruthenium complexes react preferentially with olefins and can, indeed, be used in aqueous media for metathesis reactions”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [144]
Citations
Cites
Comprehensive Organometallic Chemistry
Seyferth, D. (1984) · Organometallics · doi:10.1021/om00085a900 · Cited by 4,774
Comprehensive Organometallic Chemistry
(1982) · Chemical & Engineering News · doi:10.1021/cen-v060n019.p050 · Cited by 2,268
Nguyen, S. T., Johnson, L. K., Grubbs, R. H., & Ziller, J. W. (1992) · Journal of the American Chemical Society · doi:10.1021/ja00036a053 · Cited by 1,010
Self-citationPolymerization of Propene and Butene with a Chiral Zirconocene and Methylalumoxane as Cocatalyst
Kaminsky, W., Külper, K., Brintzinger, H. H., & Wild, F. R. W. P. (1985) · Angewandte Chemie International Edition in English · doi:10.1002/anie.198505071 · Cited by 896
Syntheses and activities of new single-component, ruthenium-based olefin metathesis catalysts
Nguyen, S. T., Grubbs, R. H., & Ziller, J. W. (1993) · Journal of the American Chemical Society · doi:10.1021/ja00074a086 · Cited by 709
Self-citationCatalytic ring-closing metathesis of functionalized dienes by a ruthenium carbene complex
Fu, G. C., Nguyen, S. T., & Grubbs, R. H. (1993) · Journal of the American Chemical Society · doi:10.1021/ja00074a085 · Cited by 548
Self-citationTitanacyclobutanes derived from strained, cyclic olefins: the living polymerization of norbornene
Gilliom, L. R., & Grubbs, R. H. (1986) · Journal of the American Chemical Society · doi:10.1021/ja00264a027 · Cited by 407
Self-citationSchrock, R. R., Depue, R. T., Feldman, J., Schaverien, C. J., Dewan, J. C., & Liu, A. H. (1988) · Journal of the American Chemical Society · doi:10.1021/ja00213a014 · Cited by 318
Novak, B. M., & Grubbs, R. H. (1988) · Journal of the American Chemical Society · doi:10.1021/ja00230a047 · Cited by 259
Self-citationSchaverien, C. J., Dewan, J. C., & Schrock, R. R. (1986) · Journal of the American Chemical Society · doi:10.1021/ja00270a056 · Cited by 250
Research works printed but not linked: 1
- Sinn H., 1980, Adv. Organo-met. Chem., 18, 390
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Sorted by citations
The Development of L 2 X 2 RuCHR Olefin Metathesis Catalysts: An Organometallic Success Story
Trnka, T. M., & Grubbs, R. H. (2000) · Accounts of Chemical Research · doi:10.1021/ar000114f · Cited by 3,561
Self-citationGrubbs, R. H. (2004) · Tetrahedron · doi:10.1016/j.tet.2004.05.124 · Cited by 1,205
Self-citationOlefin Metathesis in Organic Chemistry
Schuster, M., & Blechert, S. (1997) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199720361 · Cited by 902
Homogeneous Catalysis in Supercritical Fluids
Jessop, P. G., Ikariya, T., & Noyori, R. (1999) · Chemical Reviews · doi:10.1021/cr970037a · Cited by 825
Recent advances in ruthenium-based olefin metathesis
Ogba, O. M., Warner, N. C., O’Leary, D. J., & Grubbs, R. H. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00027a · Cited by 764
Self-citation
Metadata
- Authors
- Grubbs, R. H.
- Corresponding author
- Grubbs, Robert H.
- ORCID
- Grubbs, Robert H.
- Venue
- Journal of Macromolecular Science, Part A
- Publisher
- Informa UK Limited
- Published
- 1994-01
- Volume
- 31
- Issue
- 11
- Pages
- 1829-1933
- ISSN
- 1060-1325 (ISSN-L)
- 1520-5738
- OpenAlex
- W2036675572
- Cited by
- 95
- References
- 19
- Citations by year
- 2026: 1 · 2025: 3 · 2024: 2 · 2023: 5 · 2022: 3 · 2021: 5 · 2020: 3 · 2019: 5 · 2018: 5 · 2017: 3 · 2016: 3 · 2013: 3 · 2012: 5
- FWCI
- 2.16
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Macromolecular Science Part A (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Synthetic Organic Chemistry Methods
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Keywords
- ring-opening metathesis polymerization, functional group tolerance, metathesis catalysts, carbene complexes, metallacycles, living polymerization, olefin metathesis, Ziegler-type catalysts, organometallic complexes
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