Cited by 96Synthetic Organic Chemistry MethodsOrganometallic Complex Synthesis and CatalysisAdvanced Polymer Synthesis and Characterization

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The Development of Functional Group Tolerant Romp Catalysts

Grubbs, Robert H.·1994·Journal of Macromolecular Science, Part A

DOI 10.1080/10601329408545884

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Abstract

Since the discovery that transition metals salts mixed with organoaluminum reagents catalyze the polymerization of ethylene to crystalline polyethylene, organo-metallic complexes and reagents have played a major role in the polymer industry [1]. Over the past 20 years a tremendous amount has been learned about the structures and mechanisms of reactions of complexes related to those proposed to be active in these systems [2]. In the related area of olefin metathesis and ring-opening metathesis polymerization (ROMP), metal carbenes and metallacycles were proposed intermediates, and over the past few years a number of complexes with these structures that will catalyze the olefin metathesis reaction have been prepared and studied [3]. In contrast to the ill-defined classical catalysts based on Ziegler-type catalysts, these are living polymerization systems. This was first observed using Tebbe-type reagents [4].

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Authors: Grubbs, R. H.
Corresponding author: Grubbs, Robert H.
ORCID: Grubbs, Robert H.
Venue: Journal of Macromolecular Science, Part A
Publisher: Informa UK Limited
Published: 1994-01
Volume: 31
Issue: 11
Pages: 1829-1933
ISSN: 1060-1325 (ISSN-L)
1520-5738
DOI: 10.1080/10601329408545884
OpenAlex: W2036675572
Cited by: 95
References: 19
Citations by year: 2026: 1 · 2025: 3 · 2024: 2 · 2023: 5 · 2022: 3 · 2021: 5 · 2020: 3 · 2019: 5 · 2018: 5 · 2017: 3 · 2016: 3 · 2013: 3 · 2012: 5
FWCI: 2.16
Type: journal article
Language: en
Open access: closed
Locations: Journal of Macromolecular Science Part A (publishedVersion)
Topics: Physical Sciences › Chemistry › Organic Chemistry › Synthetic Organic Chemistry Methods
Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
Keywords: ring-opening metathesis polymerization, functional group tolerance, metathesis catalysts, carbene complexes, metallacycles, living polymerization, olefin metathesis, Ziegler-type catalysts, organometallic complexes

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The Development of Functional Group Tolerant Romp Catalysts

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