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The Photooxidative Degradation of Polypropylene. Part I. Photooxidation and Photoinitiation Processes
Abstract
All unstabilized organic polymers are degraded upon exposure to terrestrial sunlight in the presence of oxygen. However, the rates of photooxidative deterioration vary enormously with polymer structure, and range from a few months outdoor lifetime for polypropylene (PPH) and poly(l,3-phenylene isophthalamide) up to several years for poly(ethylene terephthalate), poly(methyl methylacrylate), and poly-(tetrafluoroethylene). Despite its high photosensitivity, PPH is now widely exploited in the form of films, fibers, and moldings. Current PPH capacity in the United States is rated at ∼1.2 × 106 metric tons, of which −30% is used as thin films and fibers [1].
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Cites
Physical and chemical properties of singlet molecular oxygen
Kearns, D. R. (1971) · Chemical Reviews · doi:10.1021/cr60272a004 · Cited by 913
Cited by
Mechanistic implications of plastic degradation
Singh, B., & Sharma, N. (2008) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2007.11.008 · Cited by 1,569
Tidjani, A. (2000) · Polymer Degradation and Stability · doi:10.1016/s0141-3910(00)00039-2 · Cited by 166
Thermal and mechanical properties of polypropylene/wood‐flour composites
Ndiaye, D., Matuana, L. M., Morlat‐Therias, S., Vidal, L., Tidjani, A., & Gardette, J. (2011) · Journal of Applied Polymer Science · doi:10.1002/app.32985 · Cited by 59
Investigation on the Durability of a Polypropylene Geotextile under Artificial Aging Scenarios
Scholz, P., Falkenhagen, J., Wachtendorf, V., Brüll, R., & Simon, F.-G. (2024) · Sustainability · doi:10.3390/su16093559 · Cited by 11
Metadata
- Authors
- Carlsson, D. J., & Wiles, D. M.
- Venue
- Journal of Macromolecular Science, Part C: Polymer Reviews
- Publisher
- Informa UK Limited
- Published
- 1976-01
- Volume
- 14
- Issue
- 1
- Pages
- 65-106
- ISSN
- 0736-6574 (ISSN-L)
- 1532-1797
- 1520-5746
- OpenAlex
- W2314006343
- Cited by
- 314
- References
- 1
- FWCI
- 20.21
- Type
- journal article
- Language
- en
- Open access
- closed
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- Carlsson, D. J., & Wiles, D. M. (1976). The Photooxidative Degradation of Polypropylene. Part I. Photooxidation and Photoinitiation Processes. Journal of Macromolecular Science, Part C: Polymer Reviews. https://doi.org/10.1080/15321797608076113
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.