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Self-Healing of Poly(Ethylene-co-Methacrylic Acid) Copolymers Following Projectile Puncture
Abstract
Several poly(ethylene-co-methacrylic acid) copolymers have shown the unique ability to self-heal following projectile puncture, with the punctured site subsequently holding pressures in excess of 3 MPa. Four specific materials (ionomers and non-ionomer copolymers) were examined to determine if ionic interactions are responsible for puncture reversal. A range of novel experiments including peel, projectile, and quantitative post-puncture testing were used to determine that ionic content is not necessary for the healing response. Mechanistically, it was concluded that healing occurs through at least a two-stage process of melt elastic recovery followed by sealing and polymer chain interdiffusion at the damaged site.
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Cited by
Self-Healing Polymers and Composites
Blaiszik, B. J., Kramer, S. L. B., Olugebefola, S. C., Moore, J. S., Sottos, N. R., & White, S. R. (2010) · Annual Review of Materials Research · doi:10.1146/annurev-matsci-070909-104532 · Cited by 1,505
Interlayer self-healing and toughening of carbon fibre/epoxy composites using copolymer films
Wang, C. H., Sidhu, K., Yang, T., Zhang, J., & Shanks, R. (2012) · Composites Part A: Applied Science and Manufacturing · doi:10.1016/j.compositesa.2011.11.020 · Cited by 114
Nji, J., & Li, G. (2012) · Smart Materials and Structures · doi:10.1088/0964-1726/21/2/025011 · Cited by 96
Ezeigwe, E. R., Dong, L., Manjunatha, R., Tan, M., Yan, W., & Zhang, J. (2021) · Nano Energy · doi:10.1016/j.nanoen.2021.105907 · Cited by 87
Mechanical properties of mendable composites containing self-healing thermoplastic agents
Pingkarawat, K., Wang, C. H., Varley, R. J., & Mouritz, A. P. (2014) · Composites Part A: Applied Science and Manufacturing · doi:10.1016/j.compositesa.2014.05.015 · Cited by 62
Metadata
- Authors
- Kalista, S. J., Ward, T. C., & Oyetunji, Z.
- Venue
- Mechanics of Advanced Materials and Structures
- Publisher
- Informa UK Limited
- Published
- 2007-06-12
- Volume
- 14
- Issue
- 5
- Pages
- 391-397
- ISSN
- 1537-6494 (ISSN-L)
- 1537-6532
- OpenAlex
- W2152773712
- Cited by
- 229
- References
- 0
- FWCI
- 6.52
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kalista, S. J., Ward, T. C., & Oyetunji, Z. (2007). Self-Healing of Poly(Ethylene-co-Methacrylic Acid) Copolymers Following Projectile Puncture. Mechanics of Advanced Materials and Structures. https://doi.org/10.1080/15376490701298819
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.