Cited by 397biodegradable polymer synthesis and propertiesPolymer crystallization and propertiesPolymer composites and self-healing

Long-Chain Aliphatic Polymers To Bridge the Gap between Semicrystalline Polyolefins and Traditional Polycondensates

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Stempfle, Florian, Ortmann, Patrick, Mecking, Stefan·2016·Chemical Reviews

Abstract

Other than their established short-chain congeners, polycondensates based on long-chain difunctional monomers are often dominated by the long methylene sequences of the repeat units in their solid-state structures and properties. This places them between traditional polycondensates and polyethylenes. The availability of long-chain monomers as a key prerequisite has benefited much from advances in the catalytic conversion of plant oils, via biotechnological and purely chemical approaches, likewise. This has promoted studies of, among others, applications-relevant properties. A comprehensive account is given of long-chain monomer syntheses and the preparation and physical properties, morphologies, mechanical behavior, and degradability of long-chain polyester, polyamides, polyurethanes, polyureas, polyacetals, and polycarbonates.

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Crossref · 10.1021/acs.chemrev.5b00705

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351 of 351 references verified0 citation errors · 0 not checkable

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  • Melting and crystallisation points of PC-18 and PE-18,18 are lowered compared to HDPE due to the energy penalty resulting from incorporation of the in-chain functional groups in crystalline lamellae.

    “As Expected, melting and crystallisation points of our PC-18 and PE-18,18 are lowered compared to HDPE due to the energy penalty 15,22 resulting from incorporation of the in-chain functional groups in crystalline lamellae”

    From Closed-loop recycling of polyethylene-like materials (2021) · cites this paper as [15]

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Authors
Stempfle, F., Ortmann, P., & Mecking, S.
Affiliations
University of Konstanz (DE)
Venue
Chemical Reviews
Published
2016-03-29
Volume
116
Issue
7
Pages
4597-4641
ISSN
  • 0009-2665 (ISSN-L)
  • 1520-6890
OpenAlex
W2318440049
Cited by
397
References
351
Citations by year
2026: 51 · 2025: 67 · 2024: 50 · 2023: 49 · 2022: 37 · 2021: 35 · 2020: 28 · 2019: 19 · 2018: 26 · 2017: 23 · 2016: 12
FWCI
1.43
Type
journal article
Language
en
Open access
Locations
  • Chemical Reviews (publishedVersion, other-oa)
  • PubMed (publishedVersion)
Topics
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
Keywords
polyesters, polyamide, polyurethane, polyurea, polyoxymethylene, polycarbonate, polycondensates, polymer morphology, mechanical properties, physical properties

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