Long-Chain Aliphatic Polymers To Bridge the Gap between Semicrystalline Polyolefins and Traditional Polycondensates
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Other than their established short-chain congeners, polycondensates based on long-chain difunctional monomers are often dominated by the long methylene sequences of the repeat units in their solid-state structures and properties. This places them between traditional polycondensates and polyethylenes. The availability of long-chain monomers as a key prerequisite has benefited much from advances in the catalytic conversion of plant oils, via biotechnological and purely chemical approaches, likewise. This has promoted studies of, among others, applications-relevant properties. A comprehensive account is given of long-chain monomer syntheses and the preparation and physical properties, morphologies, mechanical behavior, and degradability of long-chain polyester, polyamides, polyurethanes, polyureas, polyacetals, and polycarbonates.
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Melting and crystallisation points of PC-18 and PE-18,18 are lowered compared to HDPE due to the energy penalty resulting from incorporation of the in-chain functional groups in crystalline lamellae.
“As Expected, melting and crystallisation points of our PC-18 and PE-18,18 are lowered compared to HDPE due to the energy penalty 15,22 resulting from incorporation of the in-chain functional groups in crystalline lamellae”
From Closed-loop recycling of polyethylene-like materials (2021) · cites this paper as [15]
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- Authors
- Stempfle, F., Ortmann, P., & Mecking, S.
- Affiliations
- University of Konstanz (DE)
- ORCID
- Mecking, Stefan
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-03-29
- Volume
- 116
- Issue
- 7
- Pages
- 4597-4641
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2318440049
- Cited by
- 397
- References
- 351
- Citations by year
- 2026: 51 · 2025: 67 · 2024: 50 · 2023: 49 · 2022: 37 · 2021: 35 · 2020: 28 · 2019: 19 · 2018: 26 · 2017: 23 · 2016: 12
- FWCI
- 1.43
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Chemical Reviews (publishedVersion, other-oa)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Keywords
- polyesters, polyamide, polyurethane, polyurea, polyoxymethylene, polycarbonate, polycondensates, polymer morphology, mechanical properties, physical properties
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