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From Vegetable Oils to Polyurethanes: Synthetic Routes to Polyols and Main Industrial Products
Open accessAbstract
Most of biobased polyols for polyurethanes are synthesized from vegetable oils. In the first part, the present review goes into details of these different synthetic routes to obtain polyols. First, olefinic functionalities of triglycerides could easily be epoxidized, leading to reactive epoxide groups. Second, triglycerides double bonds could undergo a wide ranges of reactions to yield polyols. Finally, the carbonyl group could also be used as a reactive group to yield various polyols. In the second part, the present review is dedicated to the commercial biobased polyols, and, based on the patent literature focuses on the industrial synthetic routes.
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Cites
Plant oil renewable resources as green alternatives in polymer science
Meier, M. A. R., Metzger, J. O., & Schubert, U. S. (2007) · Chemical Society Reviews · doi:10.1039/b703294c · Cited by 1,487
Long-Chain Linear C 19 and C 23 Monomers and Polycondensates from Unsaturated Fatty Acid Esters
Stempfle, F., Quinzler, D., Heckler, I., & Mecking, S. (2011) · Macromolecules · doi:10.1021/ma200627e · Cited by 203
Cited by
Vegetable-oil-based polymers as future polymeric biomaterials
Miao, S., Wang, P., Su, Z., & Zhang, S. (2014) · Acta Biomaterialia · doi:10.1016/j.actbio.2013.08.040 · Cited by 573
Production of bioplastic through food waste valorization
Tsang, Y. F., Kumar, V., Samadar, P., Yang, Y., Lee, J., Ok, Y. S., Song, H., Kim, K.-H., Kwon, E. E., & Jeon, Y. J. (2019) · Environment International · doi:10.1016/j.envint.2019.03.076 · Cited by 480
Non-isocyanate polyurethanes: from chemistry to applications
Kathalewar, M. S., Joshi, P. B., Sabnis, A. S., & Malshe, V. C. (2013) · RSC Advances · doi:10.1039/c2ra21938g · Cited by 414
Homogeneous catalysis for the conversion of biomass and biomass-derived platform chemicals
Deuss, P. J., Barta, K., & de Vries, J. G. (2014) · Catal. Sci. Technol. · doi:10.1039/c3cy01058a · Cited by 316
Structure–properties relationship of fatty acid-based thermoplastics as synthetic polymer mimics
Maisonneuve, L., Lebarbé, T., Grau, E., & Cramail, H. (2013) · Polymer Chemistry · doi:10.1039/c3py00791j · Cited by 220
Metadata
- Authors
- Desroches, M., Escouvois, M., Auvergne, R., Caillol, S., & Boutevin, B.
- Venue
- Polymer Reviews
- Publisher
- Informa UK Limited
- Published
- 2012-01
- Volume
- 52
- Issue
- 1
- Pages
- 38-79
- ISSN
- 0736-6574 (ISSN-L)
- 1558-3724
- 1558-3716
- OpenAlex
- W2081881363
- Cited by
- 520
- References
- 2
- FWCI
- 15.51
- Type
- journal article
- Language
- en
- Open access
- green
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- Desroches, M., Escouvois, M., Auvergne, R., Caillol, S., & Boutevin, B. (2012). From Vegetable Oils to Polyurethanes: Synthetic Routes to Polyols and Main Industrial Products. Polymer Reviews. https://doi.org/10.1080/15583724.2011.640443
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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