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Structural Parameters of Perhydrous Indian Coals
Abstract
Higher hydrogen content of perhydrous coals exhibits a different composition and physicochemical properties in comparison with normal coals. In the present investigation, a structural study of perhydrous coals and coke was done using FTIR and HPLC data. These coals have high volatile matter with high-calorific values and low-moisture content. The structural study suggests that the major structural units of these coals are simple phenols with para-alkyl substituted derivatives. They have high alkyl substitution groups and low aromatic compounds. The structural studies reveal that these coals contain high amounts of low-molecular weight PAH compounds with 1-2 ring structures. These 1-2 ring structures have high H/C ratios as compared to large ring polyaromatic hydrocarbons (PAHs). It may also be one of the reasons for high H/C ratios in these coals. The alkyl groups contribute significantly to their high volatile matter (VM) contents. The presence of alcoholic groups found in pyrolytic products may also be due to the conversion of catechol-like structures to those of cresols. Coal properties, such as moisture, VM, H/C ratio, and CV, do not correlate with the rank as normally classified. A definite relationship has been found between the characteristics of these coals, char/cokes, and aromatic characters (f a , Har).
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-NH2 groups are involved in Cr(VI) sorption on RHB, as indicated by FTIR peaks at 705, 775 cm-1 before loading and 738, 834 cm-1 after loading.
“The peaks of wave numbers at 705, 775 cm À1 of Cr(VI) unloaded and at 738, 834 cm À1 after loading of Cr (VI) on surface of RHB were might be attributed to extending vibrations of -NH 2 groups showing their involvement in Cr(VI) soprtion [65].”
From Adsorption-reduction performance of tea waste and rice husk biochars for Cr(VI) elimination from wastewater (2020) · cites this paper as [65]
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Khalil, U., Bilal Shakoor, M., Ali, S., Rizwan, M., Nasser Alyemeni, M., & Wijaya, L. (2020) · Journal of Saudi Chemical Society · doi:10.1016/j.jscs.2020.07.001 · Cited by 139
“The peaks of wave numbers at 705, 775 cm (cid:1) 1 of Cr(VI) unloaded and at 738, 834 cm (cid:1) 1 after loading of Cr (VI) on surface of RHB were might be attributed to extending vibrations of –NH 2 groups showing their involvement in Cr(VI) soprtion [65].”
Metadata
- Authors
- Khare, P., & Baruah, B. P.
- Affiliations
- North East Institute of Science and Technology (IN)
- Corresponding author
- Khare, Puja
- Venue
- International Journal of Coal Preparation and Utilization
- Publisher
- Informa UK Limited
- Published
- 2010-05-26
- Volume
- 30
- Issue
- 1
- Pages
- 44-67
- ISSN
- 1939-2699 (ISSN-L)
- 1939-2702
- OpenAlex
- W2007861370
- Cited by
- 30
- References
- 25
- Citations by year
- 2026: 1 · 2025: 2 · 2024: 4 · 2023: 3 · 2022: 1 · 2021: 2 · 2020: 2 · 2019: 2 · 2016: 3 · 2015: 2 · 2014: 3 · 2013: 4
- FWCI
- 9.05
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- International Journal of Coal Preparation and Utilization (publishedVersion)
- Topics
- Physical Sciences › Energy › Fuel Technology › Coal and Coke Industries Research
- Physical Sciences › Energy › Fuel Technology › Coal Properties and Utilization
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Coal and Its By-products
- Keywords
- Indian coal, coal structure, polycyclic aromatic hydrocarbons, low molecular weight PAHs, H/C ratio, volatile matter, calorific value, coke, char, aromatic character, phenolic compounds, alkyl substitution, coal rank
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