Cited by 100Concrete and Cement Materials ResearchMicrobial Applications in Construction MaterialsCO2 Sequestration and Geologic Interactions

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Activation of cement hydration with carbon dioxide

Monkman, Sean, Kenward, Paul A., Dipple, Greg, MacDonald, Mark, Raudsepp, Mati·2018·Journal of Sustainable Cement-Based Materials

Abstract

Additions of carbon dioxide to hydrating concrete have been observed to result in performance benefits. In this study, oil-well cement (selected for its very low initial carbonate content) was hydrated in the presence and absence of pure CO2 gas. The evolution of the products and reactants was assessed through isothermal calorimetry, Quantitative X-ray Diffraction (QXRD), Loss on Ignition, and Total Inorganic Carbon. A one minute exposure to carbon dioxide gas during mixing improved the heat of hydration though 24 h by 8%. The amount of C-S-H formed increased by 20%, and the estimated degree of hydration increased by 23%. The carbon dioxide promoted the formation of calcium carbonate that was observed in the sample immediately after treatment with carbon dioxide. The carbonate was initially amorphous calcium carbonate not detectable with QXRD, but it changed over 24 h to crystalline calcite (CaCO3) detectable by QXRD.

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Crossref · 10.1080/21650373.2018.1443854

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  • Several commercial efforts involving mineral carbonation sell products in the construction industry.

    “Presently, there are several commercial efforts involving MC in which products are sold in the construction industry.97,98”

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Metadata

Authors
Monkman, S., Kenward, P. A., Dipple, G., MacDonald, M., & Raudsepp, M.
Affiliations
  • CarbonCure Technologies (Canada) (CA)
  • University of British Columbia (CA)
  • Department of Earth, Ocean and Atmospheric Sciences, University of British Columbia, Vancouver, Canada
Corresponding author
Monkman, Sean
Venue
Journal of Sustainable Cement-Based Materials
Published
2018-02-28
Volume
7
Issue
3
Pages
160-181
ISSN
  • 2165-0373 (ISSN-L)
  • 2165-0381
OpenAlex
W2791092575
Cited by
100
References
2
Citations by year
2026: 16 · 2025: 20 · 2024: 18 · 2023: 17 · 2022: 10 · 2021: 6 · 2020: 5 · 2019: 5 · 2018: 3
FWCI
4.27
Type
journal article
Language
en
Open access
closed
Locations
Journal of Sustainable Cement-Based Materials (publishedVersion)
Funders
Natural Sciences and Engineering Research Council of Canada (Engage Grant EGP 54259-13)
Topics
  • Physical Sciences › Engineering › Civil and Structural Engineering › Concrete and Cement Materials Research
  • Physical Sciences › Environmental Science › Environmental Engineering › Microbial Applications in Construction Materials
  • Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
Keywords
cement hydration, CO2 activation, oil well cement, heat of hydration, calcium silicate hydrate, calcite formation, amorphous calcium carbonate, degree of hydration, inorganic carbon, concrete carbonation

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