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Physicochemical Impacts of In-Situ Mineralized CaCO3 on Very Early Hydration of Cement at Two Temperatures
Abstract
The addition of carbon dioxide to ready-mix concrete can improve its performance through in-situ mineralization of calcium carbonate. A model system of an oil-well cement paste mixed with and without additions of CO 2 gas was investigated to characterize the impacts of in-situ CO 2 mineralization on the first 15 min of hydration at 4 and 24 °C. Impacts were examined through aqueous chemistry, total inorganic carbon (TIC), stable isotope 13 C/ 12 C fractionation, loss on ignition (LOI), and scanning electron microscopy (SEM). It was demonstrated that the calcium and silicon concentrations increase immediately after the CO 2 input and declined within the first few minutes. TIC testing confirmed that the mineralization was rapid and brief with no evidence of increasing carbonate formation in the minutes after the CO 2 input. Isotope fractionation confirmed that the carbonates formed were attributable to the mineralization of gaseous CO 2 . The loss on ignition testing showed that the CO 2 -activated system had greater mass gain (bound water and bound CO 2 ) over 15 min of hydration than did the reference. SEM observations identified carbonate reaction products <200 nm immediately after the CO 2 injection. Gel products were formed over the ensuing 15 min. The temperature of the testing had little impact other than to increase the concentrations of Ca and Si in solution and increase the amount of mineralized CO 2, as associated with the higher solubility of CO 2 in water as the te…
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Stable isotope analysis (13C/12C fractionation) demonstrated that newly formed carbonates in oil well cements originated directly from the injected gaseous CO2, confirming the source and mechanism of mineralization.
“Recently, stable isotope analysis (¹³C/¹²C fractionation) demonstrated that newly formed carbonates in oil well cements originated directly from the injected gaseous CO₂, confirming the source and mechanism of mineralization.”
From Isotope chemistry to trace carbon mineralization in construction materials (2026) · cites this paper as [32]
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Metadata
- Authors
- Monkman, S., Kenward, P., & Dipple, G.
- Affiliations
- CarbonCure Technologies (Canada) (CA)
- University of British Columbia (CA)
- Department of Earth, Ocean and Atmospheric Sciences, University of British Columbia, Vancouver, British Columbia, Canada V6T 1Z4
- Corresponding author
- Monkman, Sean
- ORCID
- Monkman, Sean
- Venue
- ACS Sustainable Chemistry & Engineering
- Publisher
- American Chemical Society (ACS)
- Published
- 2023-04-11
- Volume
- 11
- Issue
- 16
- Pages
- 6261-6271
- ISSN
- 2168-0485 (ISSN-L)
- OpenAlex
- W4364361883
- Cited by
- 23
- References
- 47
- Citations by year
- 2026: 7 · 2025: 7 · 2024: 8 · 2023: 1
- FWCI
- 2.69
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- ACS Sustainable Chemistry & Engineering (publishedVersion)
- Funders
- Natural Sciences and Engineering Research Council of Canada (EGP 470973-14)
- Topics
- Physical Sciences › Engineering › Civil and Structural Engineering › Concrete and Cement Materials Research
- Physical Sciences › Environmental Science › Environmental Engineering › Microbial Applications in Construction Materials
- Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
- Keywords
- calcium carbonate, cement hydration, early-age cement paste, oil well cement, CO2 injection, temperature effects, total inorganic carbon, carbon isotope fractionation, bound water, gelation
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