Cited by 185Clay minerals and soil interactionsPolymer Nanocomposites and PropertiesLayered Double Hydroxides Synthesis and Applications

The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.

The stability of halloysite nanotubes in acidic and alkaline aqueous suspensions

White, Rachel D, Bavykin, Dmitry V, Walsh, Frank C·2012·Nanotechnology

Abstract

The long term stability of natural halloysite nanotubes was studied at room temperature (22 ± 2 °C) in pure water, acidic and basic aqueous suspensions. The structural and morphological transformations of nanotubes were studied by TEM, SEM, nitrogen adsorption, XRD Raman and FTIR spectroscopy accompanied by monitoring the concentration of dissolved Si(IV) and Al(III) in solution. It has been revealed that, in 1 mol dm(-3) H(2)SO(4) solution, the dissolution of halloysite is initiated on the inner surface of nanotubes, leading to the formation of amorphous spheroidal nanoparticles of SiO(2) whereas, in 1 mol dm(-3) NaOH solution, dissolution of the inner surface of nanotubes is accompanied by the formation of Al(OH)(3) nanosheets.

Overview

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Crossref · 10.1088/0957-4484/23/6/065705

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35 of 35 references verified0 citation errors · 0 not checkable

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Research works printed but not linked: 1

  1. Robbie R A, 1979, US Geol. Surv. Bull., 1452, 456

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Metadata

Authors
White, R. D., Bavykin, D. V., & Walsh, F. C.
Affiliations
University of Southampton (GB)
Venue
Nanotechnology
Published
2012-01-17
Volume
23
Issue
6
Pages
065705
ISSN
  • 0957-4484 (ISSN-L)
  • 1361-6528
OpenAlex
W1972199881
Cited by
185
References
35
Citations by year
2026: 9 · 2025: 6 · 2024: 22 · 2023: 12 · 2022: 16 · 2021: 18 · 2020: 23 · 2019: 17 · 2018: 10 · 2017: 13 · 2016: 12 · 2015: 12 · 2014: 7 · 2013: 3 · 2012: 5
FWCI
3.49
Type
journal article
Language
en
Open access
closed
Locations
  • Nanotechnology (publishedVersion)
  • PubMed (publishedVersion)
  • ePrints Soton (University of Southampton) (acceptedVersion)
Funders
Engineering and Physical Sciences Research Council (EP/F044445/1)
Topics
  • Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Clay minerals and soil interactions
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer Nanocomposites and Properties
  • Physical Sciences › Materials Science › Materials Chemistry › Layered Double Hydroxides Synthesis and Applications
Keywords
halloysite nanotubes, nanotube stability, dissolution, sulfuric acid, sodium hydroxide, silica nanoparticles, structural change
MeSH terms
Clay, Acids, Alkalies, Aluminum Silicates, Suspensions, Water, Nanotubes

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