The DOI matches its Crossref record; 21 of the 21 references it cites were found in a registry or an index.
Splitting of CO2by vibrational excitation in non-equilibrium plasmas: a reaction kinetics model
Abstract
We present a zero-dimensional kinetic model of CO 2 splitting in non-equilibrium plasmas. The model includes a description of the CO 2 vibrational kinetics (25 vibrational levels up to the dissociation limit of the molecule), taking into account state-specific VT and VV relaxation reactions and the effect of vibrational excitation on other chemical reactions. The model is applied to study the reaction kinetics of CO 2 splitting in an atmospheric-pressure dielectric barrier discharge (DBD) and in a moderate-pressure microwave discharge. The model results are in qualitative agreement with published experimental works. We show that the CO 2 conversion and its energy efficiency are very different in these two types of discharges, which reflects the important dissociation mechanisms involved. In the microwave discharge, excitation of the vibrational levels promotes efficient dissociation when the specific energy input is higher than a critical value (2.0 eV/molecule under the conditions examined). The calculated energy efficiency of the process has a maximum of 23%. In the DBD, vibrationally excited levels do not contribute significantly to the dissociation of CO 2 and the calculated energy efficiency of the process is much lower (5%).
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Cites
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Cited by
The case for in situ resource utilisation for oxygen production on Mars by non-equilibrium plasmas
Guerra, V., Silva, T., Ogloblina, P., Grofulović, M., Terraz, L., Silva, M. L. D., Pintassilgo, C. D., Alves, L. L., & Guaitella, O. (2017) · Plasma Sources Science and Technology · doi:10.1088/1361-6595/aa8dcc · Cited by 72
Plasmas for in situ resource utilization on Mars: Fuels, life support, and agriculture
Guerra, V., Silva, T., Pinhão, N., Guaitella, O., Guerra-Garcia, C., Peeters, F. J. J., Tsampas, M. N., & van de Sanden, M. C. M. (2022) · Journal of Applied Physics · doi:10.1063/5.0098011 · Cited by 49
McKinney, L. G., Silva, T., Guerra, V., & Guerra-Garcia, C. (2024) · AIAA SCITECH 2024 Forum · doi:10.2514/6.2024-2243 · Cited by 3
Metadata
- Authors
- Kozák, T., & Bogaerts, A.
- Venue
- Plasma Sources Science and Technology
- Publisher
- IOP Publishing
- Published
- 2014-06-17
- Volume
- 23
- Issue
- 4
- Pages
- 045004
- ISSN
- 0963-0252 (ISSN-L)
- 1361-6595
- OpenAlex
- W2087872498
- Cited by
- 420
- References
- 21
- FWCI
- 21.17
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kozák, T., & Bogaerts, A. (2014). Splitting of CO2by vibrational excitation in non-equilibrium plasmas: a reaction kinetics model. Plasma Sources Science and Technology. https://doi.org/10.1088/0963-0252/23/4/045004
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
