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Life extension of self-healing polymers with rapidly growing fatigue cracks

Open access
Jones, A.S, Rule, J.D, Moore, J.S, Sottos, N.R, White, S.R·2007·Journal of The Royal Society Interface

Abstract

Self-healing polymers, based on microencapsulated dicyclopentadiene and Grubbs' catalyst embedded in the polymer matrix, are capable of responding to propagating fatigue cracks by autonomic processes that lead to higher endurance limits and life extension, or even the complete arrest of the crack growth. The amount of fatigue-life extension depends on the relative magnitude of the mechanical kinetics of crack propagation and the chemical kinetics of healing. As the healing kinetics are accelerated, greater fatigue life extension is achieved. The use of wax-protected, recrystallized Grubbs' catalyst leads to a fourfold increase in the rate of polymerization of bulk dicyclopentadiene and extends the fatigue life of a polymer specimen over 30 times longer than a comparable non-healing specimen. The fatigue life of polymers under extremely fast fatigue crack growth can be extended through the incorporation of periodic rest periods, effectively training the self-healing polymeric material to achieve higher endurance limits.

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Metadata

Authors
Jones, A. S., Rule, J. D., Moore, J. S., Sottos, N. R., & White, S. R.
Venue
Journal of The Royal Society Interface
Published
2006-12-19
Volume
4
Issue
13
Pages
395-403
ISSN
  • 1742-5662 (ISSN-L)
  • 1742-5689
OpenAlex
W2167364120
Cited by
184
References
2
FWCI
11.44
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Life extension of self-healing polymers with rapidly growing fatigue cracks. https://app.cochat.ai/papers/10.1098/rsif.2006.0199
The paper
Jones, A. S., Rule, J. D., Moore, J. S., Sottos, N. R., & White, S. R. (2007). Life extension of self-healing polymers with rapidly growing fatigue cracks. Journal of The Royal Society Interface. https://doi.org/10.1098/rsif.2006.0199

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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