Thermal conduction in artificial sapphire crystals at low temperatures I. Nearly perfect crystals

Abstract

In order to obtain a detailed verification of the theory of thermal conduction in dielectric crystals, measurements have been made on a number of artificial sapphire crystals between 2° and 100° K. In the region of the maximum there are variations in conductivity between crystals from different sources. The highest conductivities measured are about 140 W/cm deg., which suggests that estimates of several hundred watts for the maxima of ideal sapphire crystals are not unreasonable. At sufficiently low temperatures the conductivity of a very perfect, long crystal with rough surfaces is observed, in agreement with Casimir’s theory of boundary scattering, to be proportional to T3 and to the radius; the phonon mean free path is then nearly equal to the crystal diameter. Imperfect crystals show some anomalous effects. The extension of Casimir’s theory to apply to short specimens has been verified. Perfect crystals with smooth surfaces exhibit some specular reflexion of phonons; a statistical description of the surface is proposed which leads to the observed variation of this effect with temperature and is compatible with the results of interferometric examination of the surface.