The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Tin-containing silicates: structure–activity relations
Open accessAbstract
The selective conversion of biomass-derived substrates is one of the major challenges facing the chemical industry. Recently, stannosilicates have been employed as highly active and selective Lewis acid catalysts for a number of industrially relevant reactions. In the present work, four different stannosilicates have been investigated: Sn-BEA, Sn-MFI, Sn-MCM-41 and Sn-SBA-15. When comparing the properties of tin sites in the structures, substantial differences are observed. Sn-beta displays the highest Lewis acid strength, as measured by probe molecule studies using infrared spectroscopy, which gives it a significantly higher activity at low temperatures than the other structures investigated. Furthermore, the increased acid strength translates into large differences in selectivity between the catalysts, thus demonstrating the influence of the structure on the active site, and pointing the way forward for tailoring the active site to the desired reaction.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Ethyl lactate as a solvent: Properties, applications and production processes – a review
Pereira, C. S. M., Silva, V. M. T. M., & Rodrigues, A. E. (2011) · Green Chemistry · doi:10.1039/c1gc15523g · Cited by 544
Cited by
Single-Atom Catalysts across the Periodic Table
Kaiser, S. K., Chen, Z., Faust Akl, D., Mitchell, S., & Pérez-Ramírez, J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00576 · Cited by 1,367
Gallo, J. M. R., Alonso, D. M., Mellmer, M. A., & Dumesic, J. A. (2013) · Green Chem. · doi:10.1039/c2gc36536g · Cited by 355
Catalytic Isomerization of Biomass‐Derived Aldoses: A Review
Delidovich, I., & Palkovits, R. (2016) · ChemSusChem · doi:10.1002/cssc.201501577 · Cited by 300
Iglesias, J., Martínez-Salazar, I., Maireles-Torres, P., Martin Alonso, D., Mariscal, R., & López Granados, M. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00177e · Cited by 292
Metadata
- Authors
- Osmundsen, C. M., Holm, M. S., Dahl, S., & Taarning, E.
- Venue
- Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences
- Publisher
- The Royal Society
- Published
- 2012-02-29
- Volume
- 468
- Issue
- 2143
- Pages
- 2000-2016
- ISSN
- 1364-5021 (ISSN-L)
- 1471-2946
- OpenAlex
- W2143905520
- Cited by
- 171
- References
- 1
- FWCI
- 9.27
- Type
- journal article
- Language
- en
- Open access
- bronze
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Tin-containing silicates: structure–activity relations. https://app.cochat.ai/papers/10.1098/rspa.2012.0047
- The paper
- Osmundsen, C. M., Holm, M. S., Dahl, S., & Taarning, E. (2012). Tin-containing silicates: structure–activity relations. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences. https://doi.org/10.1098/rspa.2012.0047
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
