A Collective Description of Electron Interactions: IV. Electron Interaction in Metals

Abstract

The effects of the Coulomb interaction between free electrons in an electron gas are considered for a variety of phenomena. The analysis is based on the collective description, which describes the long-range correlations in electronic positions (due to the Coulomb force) in terms of the collective oscillations of the system as a whole. It is shown that an independent electron model should provide a good description of the electrons in a metal in many cases of interest. The ground state energy of the free electron gas is determined, and an estimate of the correlation energy is obtained, with results in good agreement with those of Wigner. The exchange energy is shown to be greatly reduced by the long-range correlations, so that its effect on the level density and the specific heat is comparatively slight, leading to an electronic specific heat for Na which is approximately 80 percent of the free-electron value. The possible ferromagnetism of a free-electron gas is investigated, and it is found that the long-range Coulomb correlations are such that a free-electron gas will never become ferromagnetic (no matter how low the density). The excitation of the collective oscillations by a fast charged particle is studied, and the semiclassical results obtained by Bohm and Pines are verified by a quantum-mechanical calculation. The results are applied to the experiments of Ruthermann and Lang on the scattering of electrons by thin metallic films and to experiments on the stopping power of light metals for fast charged particles, with resulting good agreement between theory and experiment.