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Theory of relativistic effects on atoms: Configuration-space Hamiltonian
Abstract
The configuration-space Hamiltonian for a many-electron atom is derived clearing up some of the ambiguities concerning the projection operators which must occur in this Hamiltonian. In the process, numerical calculations which have been previously performed are justified. The elementary two-electron interaction in the presence of many other electrons is also discussed.
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Citations
Cites
Quantum Mechanics of One- and Two-Electron Atoms
Bethe, H. A., & Salpeter, E. E. (1957) · doi:10.1007/978-3-662-12869-5 · Cited by 4,758
Sakurai, J. J., & Freedman, D. Z. (1968) · American Journal of Physics · doi:10.1119/1.1974573 · Cited by 2,022
Cited by
Relativistic Hamiltonians for Chemistry: A Primer
Saue, T. (2011) · ChemPhysChem · doi:10.1002/cphc.201100682 · Cited by 512
Diagonalisation of the Dirac Hamiltonian as a basis for a relativistic many-body procedure
Heully, J. L., Lindgren, I., Lindroth, E., Lundqvist, S., & Martensson-Pendrill, A. M. (1986) · Journal of Physics B: Atomic and Molecular Physics · doi:10.1088/0022-3700/19/18/011 · Cited by 416
Photoionization of atoms using synchrotron radiation
Schmidt, V (1992) · Reports on Progress in Physics · doi:10.1088/0034-4885/55/9/003 · Cited by 388
Perspectives of relativistic quantum chemistry: the negative energy cat smiles
Liu, W. (2012) · Phys. Chem. Chem. Phys. · doi:10.1039/c1cp21718f · Cited by 76
Metadata
- Authors
- Mittleman, M. H.
- Venue
- Physical Review A
- Publisher
- American Physical Society (APS)
- Published
- 1981-09-01
- Volume
- 24
- Issue
- 3
- Pages
- 1167-1175
- ISSN
- 0556-2791 (ISSN-L)
- OpenAlex
- W1992131015
- Cited by
- 317
- References
- 2
- FWCI
- 7.17
- Type
- journal article
- Language
- en
- Open access
- closed
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- Mittleman, M. H. (1981). Theory of relativistic effects on atoms: Configuration-space Hamiltonian. Physical Review A. https://doi.org/10.1103/physreva.24.1167
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