Student or educator? Sign up with your school email and get 6 months of Pro free.
CoChat
Sign Up
Cited by 520

The DOI matches its Crossref record; 19 of the 19 references it cites were found in a registry or an index.

Intrinsic defects of TiO2(110): Interaction with chemisorbedO2,H2, CO, and CO2

Göpel, W., Rocker, G., Feierabend, R.·1983·Physical Review B
DOI 10.1103/physrevb.28.3427
Open this paper in CoChat — free account

Abstract

The interaction of Ti${\mathrm{O}}_{2}$(110) with ${\mathrm{O}}_{2}$, ${\mathrm{H}}_{2}$, CO, and C${\mathrm{O}}_{2}$ was studied by means of low-energy electron diffraction, x-ray photoelectron spectroscopy, electron energy-loss spectroscopy, thermal desorption, electron paramagnetic resonance, and measurements of changes in surface conductivities, $\ensuremath{\Delta}\ensuremath{\sigma}$, and work functions, $\ensuremath{\Delta}\ensuremath{\phi}$, for $300\ensuremath{\le}T\ensuremath{\le}1000$ K with particular emphasis on surface reactions involving intrinsic surface defects $2{\mathrm{Ti}}^{3+}\ifmmode\cdot\else\textperiodcentered\fi{}V_{O}^{}{}_{}{}^{(+)}$. The defects are thermodynamically stable at high temperatures and act as donors and specific adsorption sites for ${\mathrm{H}}_{2}$ and CO. Surface and subsurface reactions involving ${\mathrm{O}}_{2}$, ${\mathrm{H}}_{2}$, CO, and C${\mathrm{O}}_{2}$ can be separated from each other by analyzing the $\ensuremath{\Delta}\ensuremath{\sigma}$ and $\ensuremath{\Delta}\ensuremath{\phi}$ effects in a charge-transfer model, which takes into account surface and bulk electronic states in the band gap attributed to the different defects formed during the interaction.

Overview

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1103/physrevb.28.3427

Cites

19 of 19 references verified0 citation errors · 0 not checkable

Statistics

Verification

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Citations

Cites

Cited by

See all 520

Metadata

Authors
Göpel, W., Rocker, G., & Feierabend, R.
Venue
Physical Review B
Publisher
American Physical Society (APS)
Published
1983-09-15
Volume
28
Issue
6
Pages
3427-3438
ISSN
0163-1829 (ISSN-L)
DOI
10.1103/physrevb.28.3427
OpenAlex
W88755899
Cited by
520
References
19
FWCI
9.81
Type
journal article
Language
en
Open access
closed

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.