The DOI matches its Crossref record; 14 of the 14 references it cites were found in a registry or an index.
Studies of copper valence states with CuL3x-ray-absorption spectroscopy
Open accessAbstract
We have used x-ray-absorption spectroscopy to study a series of compounds in which Cu assumes a formal valence between 0 and 3. We find that the shape, the threshold energy, and the intensity of the Cu ${L}_{3}$ absorption edge is strongly influenced by the chemical state of the Cu atoms. We use the Cu 2p x-ray-absorption spectra of a large number of Cu compounds, including sulfides, oxides, La-Sr-Cu-O compounds, a phthalocyanine complex, and various minerals to show that the presence of a strong 2p-3d excitonic transition is a fingerprint of the Cu(${d}^{9}$) contribution to the ground state. A simple ionic picture is generally inadequate to describe these compounds.
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Cited by
De Luna, P., Quintero-Bermudez, R., Dinh, C.-T., Ross, M. B., Bushuyev, O. S., Todorović, P., Regier, T., Kelley, S. O., Yang, P., & Sargent, E. H. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0018-9 · Cited by 1,046
Compound Copper Chalcogenide Nanocrystals
Coughlan, C., Ibáñez, M., Dobrozhan, O., Singh, A., Cabot, A., & Ryan, K. M. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00376 · Cited by 930
Oxygen K-edge X-ray Absorption Spectra
Frati, F., Hunault, M. O. J. Y., & de Groot, F. M. F. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00439 · Cited by 768
Self-citationX-ray absorption and dichroism of transition metals and their compounds
de Groot, F. M. F. (1994) · Journal of Electron Spectroscopy and Related Phenomena · doi:10.1016/0368-2048(93)02041-j · Cited by 677
Self-citationChen, J. G. (1997) · Surface Science Reports · doi:10.1016/s0167-5729(97)00011-3 · Cited by 620
Metadata
- Authors
- Grioni, M., Goedkoop, J. B., Schoorl, R., de Groot, F. M. F., Fuggle, J. C., Schäfers, F., Koch, E. E., Rossi, G., Esteva, J.-M., & Karnatak, R. C.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 1989-01-15
- Volume
- 39
- Issue
- 3
- Pages
- 1541-1545
- ISSN
- 0163-1829 (ISSN-L)
- OpenAlex
- W2067027712
- Cited by
- 296
- References
- 14
- FWCI
- 14.83
- Type
- journal article
- Language
- en
- Open access
- green
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- Grioni, M., Goedkoop, J. B., Schoorl, R., de Groot, F. M. F., Fuggle, J. C., Schäfers, F., Koch, E. E., Rossi, G., Esteva, J.-M., & Karnatak, R. C. (1989). Studies of copper valence states with CuL3x-ray-absorption spectroscopy. Physical Review B. https://doi.org/10.1103/physrevb.39.1541
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