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Cited by 345

The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.

Electron-energy-loss core-edge structures in manganese oxides

Kurata, Hiroki, Colliex, Christian·1993·Physical Review B

Abstract

Oxygen K and manganese ${\mathit{L}}_{2,3}$ edges electron-energy-loss spectra have been measured for a series of manganese oxides with different nominal oxidation states for the cation (MnO, ${\mathrm{Mn}}_{3}$${\mathrm{O}}_{4}$, ${\mathrm{Mn}}_{2}$${\mathrm{O}}_{3}$, ${\mathrm{MnO}}_{2}$, and ${\mathrm{BaMnO}}_{4}$). Spectra have been processed for quantitative elemental analysis and for the evaluation of manganese ${\mathit{L}}_{2,3}$ white-line intensity ratios and normalized total intensities. Prepeaks on the oxygen K edge are sensitive to the nature of local chemical bonds and their detailed substructures are interpreted with the support of a molecular-orbital picture. As for the cation point of view, the analysis of the white-line intensities provides a satisfactory measurement of the effective 3d orbital occupancy as well as a hint of the local magnetic properties. The present study also confirms that the hybridization between oxygen 2p and manganese 3d orbitals plays an important role when considering the electronic structures of these oxides.

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Metadata

Authors
Kurata, H., & Colliex, C.
Venue
Physical Review B
Published
1993-07-15
Volume
48
Issue
4
Pages
2102-2108
ISSN
  • 0163-1829 (ISSN-L)
  • 1095-3795
OpenAlex
W2024604386
Cited by
345
References
8
FWCI
5.32
Type
journal article
Language
en
Open access
closed

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