The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Electron-energy-loss core-edge structures in manganese oxides
Abstract
Oxygen K and manganese ${\mathit{L}}_{2,3}$ edges electron-energy-loss spectra have been measured for a series of manganese oxides with different nominal oxidation states for the cation (MnO, ${\mathrm{Mn}}_{3}$${\mathrm{O}}_{4}$, ${\mathrm{Mn}}_{2}$${\mathrm{O}}_{3}$, ${\mathrm{MnO}}_{2}$, and ${\mathrm{BaMnO}}_{4}$). Spectra have been processed for quantitative elemental analysis and for the evaluation of manganese ${\mathit{L}}_{2,3}$ white-line intensity ratios and normalized total intensities. Prepeaks on the oxygen K edge are sensitive to the nature of local chemical bonds and their detailed substructures are interpreted with the support of a molecular-orbital picture. As for the cation point of view, the analysis of the white-line intensities provides a satisfactory measurement of the effective 3d orbital occupancy as well as a hint of the local magnetic properties. The present study also confirms that the hybridization between oxygen 2p and manganese 3d orbitals plays an important role when considering the electronic structures of these oxides.
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Cites
Oxygen 1 s x-ray-absorption edges of transition-metal oxides
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Electron-energy-loss-spectroscopy near-edge fine structures in the iron-oxygen system
Colliex, C., Manoubi, T., & Ortiz, C. (1991) · Physical Review B · doi:10.1103/physrevb.44.11402 · Cited by 391
Self-citationGrunes, L. A., Leapman, R. D., Wilker, C. N., Hoffmann, R., & Kunz, A. B. (1982) · Physical review. B, Condensed matter · doi:10.1103/physrevb.25.7157 · Cited by 342
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Wang, Z. L. (2000) · The Journal of Physical Chemistry B · doi:10.1021/jp993593c · Cited by 2,137
Ferromagnetism above room temperature in bulk and transparent thin films of Mn-doped ZnO
Sharma, P., Gupta, A., Rao, K. V., Owens, F. J., Sharma, R., Ahuja, R., Guillen, J. M. O., Johansson, B., & Gehring, G. A. (2003) · Nature Materials · doi:10.1038/nmat984 · Cited by 1,757
Oxygen K-edge X-ray Absorption Spectra
Frati, F., Hunault, M. O. J. Y., & de Groot, F. M. F. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00439 · Cited by 768
Yang, W., Su, Z., Xu, Z., Yang, W., Peng, Y., & Li, J. (2020) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.118150 · Cited by 746
EELS analysis of cation valence states and oxygen vacancies in magnetic oxides
Wang, Z. L., Yin, J. S., & Jiang, Y. D. (2000) · Micron · doi:10.1016/s0968-4328(99)00139-0 · Cited by 388
Metadata
- Authors
- Kurata, H., & Colliex, C.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 1993-07-15
- Volume
- 48
- Issue
- 4
- Pages
- 2102-2108
- ISSN
- 0163-1829 (ISSN-L)
- 1095-3795
- OpenAlex
- W2024604386
- Cited by
- 345
- References
- 8
- FWCI
- 5.32
- Type
- journal article
- Language
- en
- Open access
- closed
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