The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
Oxygen-vacancy-related low-frequency dielectric relaxation and electrical conduction inBi:SrTiO3
Abstract
The temperature dependence of dielectric properties and electrical conduction of $({\mathrm{Sr}}_{1\ensuremath{-}1.5x}{\mathrm{Bi}}_{x}){\mathrm{TiO}}_{3} (0.0133<~x<~0.133)$ was measured from 10 to 800 K. Three sets of oxygen vacancies related dielectric peaks (peaks A, B, and $C)$ were observed. These peaks could be greatly suppressed or eliminated by annealing the samples in an oxidizing atmosphere, and enhanced or recreated by annealing in a reducing atmosphere. The results show that the Maxwell-Wagner polarization is not the main mechanism, and the Skanavi's model also cannot be directly applied. A tentative explanation was suggested. Peak A, observed in the temperature range of 100--350 K with the activation energy for dielectric relaxation ${E}_{\mathrm{relaxA}}=0.32--0.49$ eV, is attributed to the coupling effect of the conduction electrons with the motion of the off-centered Bi and Ti ions; the conduction carriers in this temperature range are from the first ionization of oxygen vacancies ${(V}_{o}).$ Peaks B and C are also discussed.
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Cites
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Metadata
- Authors
- Ang, C., Yu, Z., & Cross, L. E.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 2000-07-01
- Volume
- 62
- Issue
- 1
- Pages
- 228-236
- ISSN
- 0163-1829 (ISSN-L)
- 1095-3795
- OpenAlex
- W2000757875
- Cited by
- 986
- References
- 9
- FWCI
- 7.93
- Type
- journal article
- Language
- en
- Open access
- closed
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