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Cited by 507

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Plasmon resonances of silver nanowires with a nonregular cross section

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Kottmann, Jörg P., Martin, Olivier J. F., Smith, David R., Schultz, Sheldon·2001·Physical Review B

Abstract

We investigate numerically the spectrum of plasmon resonances for metallic nanowires with a nonregular cross section, in the $20--50 \mathrm{nm}$ range. We first consider the resonance spectra corresponding to nanowires whose cross sections form different simplexes. The number of resonances strongly increases when the section symmetry decreases: A cylindrical wire exhibits one resonance, whereas we observe more than five distinct resonances for a triangular particle. The spectral range covered by these different resonances becomes very large, giving to the particle-specific distinct colors. At the resonance, dramatic field enhancement is observed at the vicinity of nonregular particles, where the field amplitude can reach several hundred times that of the illumination field. This near-field enhancement corresponds to surface-enhanced Raman scattering (SERS) enhancement locally in excess of ${10}^{12}.$ The distance dependence of this enhancement is investigated and we show that it depends on the plasmon resonance excited in the particle, i.e., on the illumination wavelength. The average Raman enhancement for molecules distributed on the entire particle surface is also computed and discussed in the context of experiments in which large numbers of molecules are used.

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Metadata

Authors
Kottmann, J. P., Martin, O. J. F., Smith, D. R., & Schultz, S.
Venue
Physical Review B
Published
2001-11-08
Volume
64
Issue
23
ISSN
  • 0163-1829 (ISSN-L)
  • 1095-3795
OpenAlex
W2164459377
Cited by
507
References
49
FWCI
12.33
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Plasmon resonances of silver nanowires with a nonregular cross section. https://app.cochat.ai/papers/10.1103/physrevb.64.235402
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Kottmann, J. P., Martin, O. J. F., Smith, D. R., & Schultz, S. (2001). Plasmon resonances of silver nanowires with a nonregular cross section. Physical Review B. https://doi.org/10.1103/physrevb.64.235402

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