The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Structural phenomena associated with the spin-state transition inLaCoO3
Open accessAbstract
The structural properties of ${\mathrm{LaCoO}}_{3}$ were studied by means of high-resolution neutron powder diffraction in the temperature range $5<~T<~1000\mathrm{K}.$ Changes of the ${\mathrm{Co}}^{+3}$ spin states in this temperature interval are shown to affect not only the unit-cell volume, as previously known, but also internal parameters such as the metal-oxygen bond lengths. These data, as well as the temperature-dependent magnetic susceptibility, can be qualitatively modeled based on a three-state (low-spin, intermediate-spin, and high-spin) activated behavior, but correction terms are required for quantitative agreement. Our fits consistently indicate that the ionic radius of the intermediate-spin state (\ensuremath{\sim}0.56 \AA{}) is smaller than the low-spin/high-spin average (\ensuremath{\sim}0.58 \AA{}). We also present evidence of a third lattice anomaly, occurring around 800 K, which we attribute to the formation of oxygen vacancies.
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Cites
Shannon, R. D. (1976) · Acta Crystallographica Section A · doi:10.1107/s0567739476001551 · Cited by 66,145
An interpretation of the magnetic properties of the perovskite-type mixed crystals La1−xSrxCoO3−λ
Goodenough, J. B. (1958) · Journal of Physics and Chemistry of Solids · doi:10.1016/0022-3697(58)90107-0 · Cited by 1,395
First-Order Localized-Electron⇆Collective-Electron Transition in LaCoO3
Raccah, P. M., & Goodenough, J. B. (1967) · Physical Review · doi:10.1103/physrev.155.932 · Cited by 896
Nonstoichiometry of the perovskite-type oxides La1−xSrxCoO3−δ
Mizusaki, J., Mima, Y., Yamauchi, S., Fueki, K., & Tagawa, H. (1989) · Journal of Solid State Chemistry · doi:10.1016/0022-4596(89)90036-4 · Cited by 469
Electronic structure and spin-state transition ofLaCoO3
Abbate, M., Fuggle, J. C., Fujimori, A., Tjeng, L. H., Chen, C. T., Potze, R., Sawatzky, G. A., Eisaki, H., & Uchida, S. (1993) · Physical Review B · doi:10.1103/physrevb.47.16124 · Cited by 370
Possibility for an intermediate-spin ground state in the charge-transfer material SrCoO 3
Potze, R. H., Sawatzky, G. A., & Abbate, M. (1995) · Physical review. B, Condensed matter · doi:10.1103/physrevb.51.11501 · Cited by 366
Two Spin-State Transitions in LaCoO3
Asai, K., Yoneda, A., Yokokura, O., Tranquada, J. M., Shirane, G., & Kohn, K. (1998) · Journal of the Physical Society of Japan · doi:10.1143/jpsj.67.290 · Cited by 349
A neutron diffraction study of LaCoO3 in the temperature range 4.2 < T < 1248 K
Thornton, G., Tofield, B. C., & Hewat, A. W. (1986) · Journal of Solid State Chemistry · doi:10.1016/0022-4596(86)90035-6 · Cited by 290
Cited by
Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
Hong, W. T., Risch, M., Stoerzinger, K. A., Grimaud, A., Suntivich, J., & Shao-Horn, Y. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03869j · Cited by 2,089
Metadata
- Authors
- Radaelli, P. G., & Cheong, S.-W.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 2002-09-10
- Volume
- 66
- Issue
- 9
- ISSN
- 0163-1829 (ISSN-L)
- 1095-3795
- OpenAlex
- W1970390411
- Cited by
- 521
- References
- 8
- FWCI
- 8.86
- Type
- journal article
- Language
- en
- Open access
- green
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