The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
Two Spin-State Transitions in LaCoO3
Abstract
Neutron-diffraction measurements have revealed a new anomalous thermal lattice expansion of LaCoO 3 near 500 K that indicates the existence of a second spin-state transition, in addition to the one previously established near 100 K. The anomalous expansion and the temperature dependence of the Co magnetic moments are successfully interpreted in a wide temperature range based on a simple model assuming low-spin (LS, S =0), intermediate-spin (IS, S =1), and high-spin (HS, S =2) states of Co atoms. The first spin transition, near 100 K, is from LS to IS, and the second, near 500 K, is from IS to a mixed state of IS and HS. The fitted model parameters indicate that the initially-large energy difference between IS and HS states decreases towards zero as the second transition proceeds. The large drop in resistivity associated with the latter transition appears to be correlated with the population of the HS state.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
On the Absorption Spectra of Complex Ions II
Tanabe, Y., & Sugano, S. (1954) · Journal of the Physical Society of Japan · doi:10.1143/jpsj.9.766 · Cited by 1,806
First-Order Localized-Electron⇆Collective-Electron Transition in LaCoO3
Raccah, P. M., & Goodenough, J. B. (1967) · Physical Review · doi:10.1103/physrev.155.932 · Cited by 896
Intermediate-spin state and properties ofLaCoO3
Korotin, M. A., Ezhov, S. Y., Solovyev, I. V., Anisimov, V. I., Khomskii, D. I., & Sawatzky, G. A. (1996) · Physical Review B · doi:10.1103/physrevb.54.5309 · Cited by 839
Electronic structure and spin-state transition ofLaCoO3
Abbate, M., Fuggle, J. C., Fujimori, A., Tjeng, L. H., Chen, C. T., Potze, R., Sawatzky, G. A., Eisaki, H., & Uchida, S. (1993) · Physical Review B · doi:10.1103/physrevb.47.16124 · Cited by 370
Possibility for an intermediate-spin ground state in the charge-transfer material SrCoO 3
Potze, R. H., Sawatzky, G. A., & Abbate, M. (1995) · Physical review. B, Condensed matter · doi:10.1103/physrevb.51.11501 · Cited by 366
Electron-spectroscopy study of the semiconductor-metal transition in La1−x Srx CoO3
Chainani, A., Mathew, M., & Sarma, D. D. (1992) · Physical review. B, Condensed matter · doi:10.1103/physrevb.46.9976 · Cited by 298
Asai, K., Yokokura, O., Nishimori, N., Chou, H., Tranquada, J. M., Shirane, G., Higuchi, S., Okajima, Y., & Kohn, K. (1994) · Physical Review B · doi:10.1103/physrevb.50.3025 · Cited by 296
Self-citationA neutron diffraction study of LaCoO3 in the temperature range 4.2 < T < 1248 K
Thornton, G., Tofield, B. C., & Hewat, A. W. (1986) · Journal of Solid State Chemistry · doi:10.1016/0022-4596(86)90035-6 · Cited by 290
The rare earth cobaltates: localised or collective electron behaviour?
Thornton, G., Morrison, F. C., Partington, S., Tofield, B. C., & Williams, D. E. (1988) · Journal of Physics C Solid State Physics · doi:10.1088/0022-3719/21/15/019 · Cited by 98
Cited by
Structural phenomena associated with the spin-state transition inLaCoO3
Radaelli, P. G., & Cheong, S.-W. (2002) · Physical Review B · doi:10.1103/physrevb.66.094408 · Cited by 521
Structural details and magnetic order ofLa1−xSrxCoO3(x<~0.3)
Caciuffo, R., Rinaldi, D., Barucca, G., Mira, J., Rivas, J., Señarís-Rodríguez, M. A., Radaelli, P. G., Fiorani, D., & Goodenough, J. B. (1999) · Physical Review B · doi:10.1103/physrevb.59.1068 · Cited by 337
Orbital Ordering in Orthorhombic Perovskites
Goodenough, J. B., & Zhou, J.-S. (2007) · Journal of Materials Chemistry · doi:10.1039/b701805c · Cited by 67
Metadata
- Authors
- Asai, K., Yoneda, A., Yokokura, O., Tranquada, J. M., Shirane, G., & Kohn, K.
- Venue
- Journal of the Physical Society of Japan
- Publisher
- Physical Society of Japan
- Published
- 1998-01-15
- Volume
- 67
- Issue
- 1
- Pages
- 290-296
- ISSN
- 0031-9015 (ISSN-L)
- 1347-4073
- OpenAlex
- W2043240130
- Cited by
- 349
- References
- 9
- FWCI
- 6.71
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Two Spin-State Transitions in LaCoO3. https://app.cochat.ai/papers/10.1143/jpsj.67.290
- The paper
- Asai, K., Yoneda, A., Yokokura, O., Tranquada, J. M., Shirane, G., & Kohn, K. (1998). Two Spin-State Transitions in LaCoO3. Journal of the Physical Society of Japan. https://doi.org/10.1143/jpsj.67.290
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
