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Determination of LA and TO phonon dispersion relations of graphene near the Dirac point by double resonance Raman scattering

Mafra, D. L., Samsonidze, G., Malard, L. M., Elias, D. C., Brant, J. C., Plentz, F., Alves, E. S., Pimenta, M. A.·2007·Physical Review B

Abstract

Raman spectroscopy was used to determine the dispersion of the longitudinal acoustic (LA) and in-plane transverse optic phonon branches near the Dirac $K$ point of monolayer graphene from the analysis of the dispersion of two second-order Raman peaks involving the LA and TO phonons. We show that the velocities of the phonons involved in the double resonance Raman process are given by ${v}_{\mathit{LA}}=7.70\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}3}{v}_{F}$ and ${v}_{\mathit{TO}}=5.47\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}3}{v}_{F}$, where ${v}_{F}$ is the Fermi velocity of the associated electrons. The experimental results for the phonon dispersion in monolayer graphene are compared with those for turbostratic graphite and also with different theoretical models.

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Metadata

Authors
Mafra, D. L., Samsonidze, G., Malard, L. M., Elias, D. C., Brant, J. C., Plentz, F., Alves, E. S., & Pimenta, M. A.
Venue
Physical Review B
Published
2007-12-13
Volume
76
Issue
23
ISSN
  • 1098-0121 (ISSN-L)
  • 1550-235X
OpenAlex
W2072240475
Cited by
191
References
1
FWCI
4.02
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Determination of LA and TO phonon dispersion relations of graphene near the Dirac point by double resonance Raman scattering. https://app.cochat.ai/papers/10.1103/physrevb.76.233407
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Mafra, D. L., Samsonidze, G., Malard, L. M., Elias, D. C., Brant, J. C., Plentz, F., Alves, E. S., & Pimenta, M. A. (2007). Determination of LA and TO phonon dispersion relations of graphene near the Dirac point by double resonance Raman scattering. Physical Review B. https://doi.org/10.1103/physrevb.76.233407

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