The DOI matches its Crossref record; 31 of the 31 references it cites were found in a registry or an index.
Interaction, growth, and ordering of epitaxial graphene on SiC{0001} surfaces: A comparative photoelectron spectroscopy study
Abstract
Thermally induced growth of graphene on the two polar surfaces of $6H\text{\ensuremath{-}}\mathrm{Si}\mathrm{C}$ is investigated with emphasis on the initial stages of growth and interface structure. The experimental methods employed are angle-resolved valence band photoelectron spectroscopy, soft x-ray induced core-level spectroscopy, and low-energy electron diffraction. On the Si-terminated (0001) surface, the $(6\sqrt{3}\ifmmode\times\else\texttimes\fi{}6\sqrt{3})R30\ifmmode^\circ\else\textdegree\fi{}$ reconstruction is the precursor of the growth of graphene and it persists at the interface upon the growth of few layer graphene (FLG). The $(6\sqrt{3}\ifmmode\times\else\texttimes\fi{}6\sqrt{3})R30\ifmmode^\circ\else\textdegree\fi{}$ structure is a carbon layer with graphene-like atomic arrangement covalently bonded to the substrate where it is responsible for the azimuthal ordering of FLG on SiC(0001). In contrast, the interaction between graphene and the C-terminated $(000\overline{1})$ surface is much weaker, which accounts for the low degree of order of FLG on this surface. A model for the growth of FLG on SiC{0001} is developed, wherein each new graphene layer is formed at the bottom of the existing stack rather than on its top. This model yields, in conjunction with the differences in the interfacial bonding strength, a natural explanation for the different degrees of azimuthal order observed for FLG on the two surfaces.
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Cites
Electric Field Effect in Atomically Thin Carbon Films
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Unconventional quantum Hall effect and Berry’s phase of 2π in bilayer graphene
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Presser, V., Heon, M., & Gogotsi, Y. (2011) · Advanced Functional Materials · doi:10.1002/adfm.201002094 · Cited by 678
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Band Alignment and Minigaps in Monolayer MoS2-Graphene van der Waals Heterostructures
Pierucci, D., Henck, H., Avila, J., Balan, A., Naylor, C. H., Patriarche, G., Dappe, Y. J., Silly, M. G., Sirotti, F., Johnson, A. T. C., et al. (2016) · Nano Letters · doi:10.1021/acs.nanolett.6b00609 · Cited by 365
Adsorption of CO 2 on Graphene: A Combined TPD, XPS, and vdW-DF Study
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Metadata
- Authors
- Emtsev, K. V., Speck, F., Seyller, T., Ley, L., & Riley, J. D.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 2008-04-02
- Volume
- 77
- Issue
- 15
- ISSN
- 1098-0121 (ISSN-L)
- 1550-235X
- OpenAlex
- W2062757334
- Cited by
- 936
- References
- 31
- FWCI
- 32.84
- Type
- journal article
- Language
- en
- Open access
- closed
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- Emtsev, K. V., Speck, F., Seyller, T., Ley, L., & Riley, J. D. (2008). Interaction, growth, and ordering of epitaxial graphene on SiC{0001} surfaces: A comparative photoelectron spectroscopy study. Physical Review B. https://doi.org/10.1103/physrevb.77.155303
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